Highly controlled living radical polymerization through dual activation of organobismuthines

Shigeru Yamago; Eiichi Kayahara; Masashi Kotani; Biswajit Ray; Yungwan Kwak; Atsushi Goto; Takeshi Fukuda

doi:10.1002/anie.200604473

Highly controlled living radical polymerization through dual activation of organobismuthines

Shigeru Yamago^*, Eiichi Kayahara, Masashi Kotani, Biswajit Ray, Yungwan Kwak, Atsushi Goto, Takeshi Fukuda

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

136 Citations (Scopus)

Abstract

(Chemical Equation Presented) The living end: Organobismuthines promote highly controlled living radical polymerization through two activation mechanisms, namely, thermal generation and degenerative transfer (see scheme). Both conjugated and nonconjugated vinyl monomers are polymerized to give well-defined polymers with predetermined molecular weight (M_n) and low polydispersity index (PDI).

Original language	English
Pages (from-to)	1304-1306
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	8
DOIs	https://doi.org/10.1002/anie.200604473
Publication status	Published - 2007
Externally published	Yes

ASJC Scopus Subject Areas

Catalysis
General Chemistry

Keywords

Bismuth
Polymerization
Radical reactions
Reaction mechanisms

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10.1002/anie.200604473

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title = "Highly controlled living radical polymerization through dual activation of organobismuthines",

abstract = "(Chemical Equation Presented) The living end: Organobismuthines promote highly controlled living radical polymerization through two activation mechanisms, namely, thermal generation and degenerative transfer (see scheme). Both conjugated and nonconjugated vinyl monomers are polymerized to give well-defined polymers with predetermined molecular weight (Mn) and low polydispersity index (PDI).",

keywords = "Bismuth, Polymerization, Radical reactions, Reaction mechanisms",

author = "Shigeru Yamago and Eiichi Kayahara and Masashi Kotani and Biswajit Ray and Yungwan Kwak and Atsushi Goto and Takeshi Fukuda",

year = "2007",

doi = "10.1002/anie.200604473",

language = "English",

volume = "46",

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journal = "Angewandte Chemie - International Edition",

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T1 - Highly controlled living radical polymerization through dual activation of organobismuthines

AU - Yamago, Shigeru

AU - Kayahara, Eiichi

AU - Kotani, Masashi

AU - Ray, Biswajit

AU - Kwak, Yungwan

AU - Goto, Atsushi

AU - Fukuda, Takeshi

PY - 2007

Y1 - 2007

N2 - (Chemical Equation Presented) The living end: Organobismuthines promote highly controlled living radical polymerization through two activation mechanisms, namely, thermal generation and degenerative transfer (see scheme). Both conjugated and nonconjugated vinyl monomers are polymerized to give well-defined polymers with predetermined molecular weight (Mn) and low polydispersity index (PDI).

AB - (Chemical Equation Presented) The living end: Organobismuthines promote highly controlled living radical polymerization through two activation mechanisms, namely, thermal generation and degenerative transfer (see scheme). Both conjugated and nonconjugated vinyl monomers are polymerized to give well-defined polymers with predetermined molecular weight (Mn) and low polydispersity index (PDI).

KW - Bismuth

KW - Polymerization

KW - Radical reactions

KW - Reaction mechanisms

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U2 - 10.1002/anie.200604473

DO - 10.1002/anie.200604473

M3 - Article

AN - SCOPUS:34250869485

SN - 1433-7851

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JF - Angewandte Chemie - International Edition

IS - 8

ER -

Highly controlled living radical polymerization through dual activation of organobismuthines

Abstract

ASJC Scopus Subject Areas

Keywords

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