Highly enantioselective carbonyl-ene reactions catalyzed by In(III)-PyBox complex

Jun Feng Zhao; Hoi Yan Tsui; Pei Jia Wu; Jun Lu; Teck Peng Loh

doi:10.1021/ja807501a

Highly enantioselective carbonyl-ene reactions catalyzed by In(III)-PyBox complex

Jun Feng Zhao, Hoi Yan Tsui, Pei Jia Wu, Jun Lu, Teck Peng Loh^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

65 Citations (Scopus)

Abstract

A highly enantioselective carbonyl-ene reaction catalyzed by In(III)-pybox is described. Both 1,1-disubstituted alkenes and 1,1,2-trisubstituted alkenes proceeded smoothly to give the ene products in high yields up to 97% and with excellent diastereoselectivity and enantioselectivities up to >99:1 and 99%, respectively.

Original language	English
Pages (from-to)	16492-16493
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	130
Issue number	49
DOIs	https://doi.org/10.1021/ja807501a
Publication status	Published - Dec 10 2008
Externally published	Yes

ASJC Scopus Subject Areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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abstract = "A highly enantioselective carbonyl-ene reaction catalyzed by In(III)-pybox is described. Both 1,1-disubstituted alkenes and 1,1,2-trisubstituted alkenes proceeded smoothly to give the ene products in high yields up to 97% and with excellent diastereoselectivity and enantioselectivities up to >99:1 and 99%, respectively.",

author = "Zhao, {Jun Feng} and Tsui, {Hoi Yan} and Wu, {Pei Jia} and Jun Lu and Loh, {Teck Peng}",

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AU - Zhao, Jun Feng

AU - Tsui, Hoi Yan

AU - Wu, Pei Jia

AU - Lu, Jun

AU - Loh, Teck Peng

PY - 2008/12/10

Y1 - 2008/12/10

N2 - A highly enantioselective carbonyl-ene reaction catalyzed by In(III)-pybox is described. Both 1,1-disubstituted alkenes and 1,1,2-trisubstituted alkenes proceeded smoothly to give the ene products in high yields up to 97% and with excellent diastereoselectivity and enantioselectivities up to >99:1 and 99%, respectively.

AB - A highly enantioselective carbonyl-ene reaction catalyzed by In(III)-pybox is described. Both 1,1-disubstituted alkenes and 1,1,2-trisubstituted alkenes proceeded smoothly to give the ene products in high yields up to 97% and with excellent diastereoselectivity and enantioselectivities up to >99:1 and 99%, respectively.

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 49

ER -

Highly enantioselective carbonyl-ene reactions catalyzed by In(III)-PyBox complex

Abstract

ASJC Scopus Subject Areas

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