Highly versatile organostibine mediators for living radical polymerization

Shigeru Yamago; Biswajit Ray; Kazunori Iida; Jun Ichi Yoshida; Tomofumi Tada; Kazunari Yoshizawa; Yungwan Kwak; Atsushi Goto; Takeshi Fukuda

doi:10.1021/ja044787v

Highly versatile organostibine mediators for living radical polymerization

Shigeru Yamago^*, Biswajit Ray, Kazunori Iida, Jun Ichi Yoshida, Tomofumi Tada, Kazunari Yoshizawa, Yungwan Kwak, Atsushi Goto, Takeshi Fukuda

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

193 Citations (Scopus)

Abstract

A new versatile method for conducting living radical polymerization has been developed in which organostibines induce consecutive group-transfer radical reactions with alkenes. The method has been successfully applied, for the first time, to the controlled polymerization of both conjugated and unconjugated vinyl monomers, and the desired polymers with predetermined molecular weight and low polydispersity index were obtained in excellent yields. This characteristic feature of this method is exemplified in the first synthesis of block copolymers composed of conjugated and unconjugated monomers, which would be of great importance as functional smart organic nanomaterials.

Original language	English
Pages (from-to)	13908-13909
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	126
Issue number	43
DOIs	https://doi.org/10.1021/ja044787v
Publication status	Published - Nov 3 2004
Externally published	Yes

ASJC Scopus Subject Areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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abstract = "A new versatile method for conducting living radical polymerization has been developed in which organostibines induce consecutive group-transfer radical reactions with alkenes. The method has been successfully applied, for the first time, to the controlled polymerization of both conjugated and unconjugated vinyl monomers, and the desired polymers with predetermined molecular weight and low polydispersity index were obtained in excellent yields. This characteristic feature of this method is exemplified in the first synthesis of block copolymers composed of conjugated and unconjugated monomers, which would be of great importance as functional smart organic nanomaterials.",

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doi = "10.1021/ja044787v",

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T1 - Highly versatile organostibine mediators for living radical polymerization

AU - Yamago, Shigeru

AU - Ray, Biswajit

AU - Iida, Kazunori

AU - Yoshida, Jun Ichi

AU - Tada, Tomofumi

AU - Yoshizawa, Kazunari

AU - Kwak, Yungwan

AU - Goto, Atsushi

AU - Fukuda, Takeshi

PY - 2004/11/3

Y1 - 2004/11/3

N2 - A new versatile method for conducting living radical polymerization has been developed in which organostibines induce consecutive group-transfer radical reactions with alkenes. The method has been successfully applied, for the first time, to the controlled polymerization of both conjugated and unconjugated vinyl monomers, and the desired polymers with predetermined molecular weight and low polydispersity index were obtained in excellent yields. This characteristic feature of this method is exemplified in the first synthesis of block copolymers composed of conjugated and unconjugated monomers, which would be of great importance as functional smart organic nanomaterials.

AB - A new versatile method for conducting living radical polymerization has been developed in which organostibines induce consecutive group-transfer radical reactions with alkenes. The method has been successfully applied, for the first time, to the controlled polymerization of both conjugated and unconjugated vinyl monomers, and the desired polymers with predetermined molecular weight and low polydispersity index were obtained in excellent yields. This characteristic feature of this method is exemplified in the first synthesis of block copolymers composed of conjugated and unconjugated monomers, which would be of great importance as functional smart organic nanomaterials.

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EP - 13909

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 43

ER -

Highly versatile organostibine mediators for living radical polymerization

Abstract

ASJC Scopus Subject Areas

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