In situ EPR studies of electron transfer across a polarised liquid/liquid interface

Robert A.W. Dryfe; Richard D. Webster; Barry A. Coles; Richard G. Compton

doi:10.1039/a700640c

In situ EPR studies of electron transfer across a polarised liquid/liquid interface

Robert A.W. Dryfe^*, Richard D. Webster, Barry A. Coles, Richard G. Compton

^*Corresponding author for this work

University of Oxford

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

The design and operation of the first ever in situ EPR cell for studying charge-transfer processes accompanying polarisation of the liquid/liquid interface is presented as well as EPR absorption data obtained from the reduction of TCNQ (to TCNQ^•-) and the oxidation of TTF (to TTP^•+) by the ferro-ferri-cyanide redox couple at the water/1,2-dichloroethane interface.

Original language	English
Pages (from-to)	779-780
Number of pages	2
Journal	Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/a700640c
Publication status	Published - 1997
Externally published	Yes

ASJC Scopus Subject Areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/a700640c

Cite this

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title = "In situ EPR studies of electron transfer across a polarised liquid/liquid interface",

abstract = "The design and operation of the first ever in situ EPR cell for studying charge-transfer processes accompanying polarisation of the liquid/liquid interface is presented as well as EPR absorption data obtained from the reduction of TCNQ (to TCNQ•-) and the oxidation of TTF (to TTP•+) by the ferro-ferri-cyanide redox couple at the water/1,2-dichloroethane interface.",

author = "Dryfe, {Robert A.W.} and Webster, {Richard D.} and Coles, {Barry A.} and Compton, {Richard G.}",

year = "1997",

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AU - Dryfe, Robert A.W.

AU - Webster, Richard D.

AU - Coles, Barry A.

AU - Compton, Richard G.

PY - 1997

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N2 - The design and operation of the first ever in situ EPR cell for studying charge-transfer processes accompanying polarisation of the liquid/liquid interface is presented as well as EPR absorption data obtained from the reduction of TCNQ (to TCNQ•-) and the oxidation of TTF (to TTP•+) by the ferro-ferri-cyanide redox couple at the water/1,2-dichloroethane interface.

AB - The design and operation of the first ever in situ EPR cell for studying charge-transfer processes accompanying polarisation of the liquid/liquid interface is presented as well as EPR absorption data obtained from the reduction of TCNQ (to TCNQ•-) and the oxidation of TTF (to TTP•+) by the ferro-ferri-cyanide redox couple at the water/1,2-dichloroethane interface.

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DO - 10.1039/a700640c

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JO - Chemical Communications

JF - Chemical Communications

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ER -

In situ EPR studies of electron transfer across a polarised liquid/liquid interface

Abstract

ASJC Scopus Subject Areas

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