InCl3-Promoted Allylation of Aldehydes in Ionic Liquid: Scope and Enantioselectivity Studies

Jun Lu; Shun Jun Ji; Rong Qian; Jian Ping Chen; Yu Liu; Teck Peng Loh

doi:10.1055/s-2004-815433

InCl₃-Promoted Allylation of Aldehydes in Ionic Liquid: Scope and Enantioselectivity Studies

Jun Lu, Shun Jun Ji^*, Rong Qian, Jian Ping Chen, Yu Liu, Teck Peng Loh

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Indium trichloride was successfully applied to allylation reaction of aldehydes using allytributyltin in ionic liquids. This accelerated catalytic system afforded the allylated products of various aldehydes in moderate to high yields. Preliminary studies on the enantioselectivity of this type of reaction have resulted in low to moderate enantioselectivities.

Original language	English
Pages (from-to)	534-536
Number of pages	3
Journal	Synlett
Issue number	3
DOIs	https://doi.org/10.1055/s-2004-815433
Publication status	Published - Feb 18 2004
Externally published	Yes

ASJC Scopus Subject Areas

Organic Chemistry

Keywords

Aldehydes
Allylation
Catalyst
Indium trichloride
Ionic liquid

Access to Document

10.1055/s-2004-815433

Cite this

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abstract = "Indium trichloride was successfully applied to allylation reaction of aldehydes using allytributyltin in ionic liquids. This accelerated catalytic system afforded the allylated products of various aldehydes in moderate to high yields. Preliminary studies on the enantioselectivity of this type of reaction have resulted in low to moderate enantioselectivities.",

keywords = "Aldehydes, Allylation, Catalyst, Indium trichloride, Ionic liquid",

author = "Jun Lu and Ji, \{Shun Jun\} and Rong Qian and Chen, \{Jian Ping\} and Yu Liu and Loh, \{Teck Peng\}",

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T2 - Scope and Enantioselectivity Studies

AU - Lu, Jun

AU - Ji, Shun Jun

AU - Qian, Rong

AU - Chen, Jian Ping

AU - Liu, Yu

AU - Loh, Teck Peng

PY - 2004/2/18

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N2 - Indium trichloride was successfully applied to allylation reaction of aldehydes using allytributyltin in ionic liquids. This accelerated catalytic system afforded the allylated products of various aldehydes in moderate to high yields. Preliminary studies on the enantioselectivity of this type of reaction have resulted in low to moderate enantioselectivities.

AB - Indium trichloride was successfully applied to allylation reaction of aldehydes using allytributyltin in ionic liquids. This accelerated catalytic system afforded the allylated products of various aldehydes in moderate to high yields. Preliminary studies on the enantioselectivity of this type of reaction have resulted in low to moderate enantioselectivities.

KW - Aldehydes

KW - Allylation

KW - Catalyst

KW - Indium trichloride

KW - Ionic liquid

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