Incorporation of conductive internal additives within electrocuring adhesives

L. Gan; N. C.S. Tan; T. W.J. Steele

doi:10.1149/07711.0981ecst

Incorporation of conductive internal additives within electrocuring adhesives

L. Gan, N. C.S. Tan, T. W.J. Steele^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

7 Citations (Scopus)

Abstract

Aryl diazirine-grafted polyamidoamine (Dz-g-PAMAM) was recently investigated as an adhesive cured with low voltage potentials, leading to a concept of electrocuring adhesive. Ferrocene is a well-known redox active compound with a high degree of electron reversibility. Ferrocene is incorporated into the electrocuring adhesive as a conductive internal additive, attempting to improve the electron transfer efficiency. In this work, the synthesis of co-grafted Dz-g-Fc-g-PAMAM is confirmed by NMR and UV/Visible absorbance compares the optical properties with and without the ferrocene internal additive.

Original language	English
Title of host publication	Selected Proceedings from the 231st ECS Meeting New Orleans, LA - Spring 2017
Publisher	Electrochemical Society Inc.
Pages	981-988
Number of pages	8
Edition	11
ISBN (Electronic)	9781607688174
ISBN (Print)	9781623324605
DOIs	https://doi.org/10.1149/07711.0981ecst
Publication status	Published - 2017
Externally published	Yes
Event	231st ECS Meeting - New Orleans, United States Duration: May 28 2017 → Jun 1 2017

Publication series

Name	ECS Transactions
Number	11
Volume	77
ISSN (Print)	1938-6737
ISSN (Electronic)	1938-5862

Conference

Conference	231st ECS Meeting
Country/Territory	United States
City	New Orleans
Period	5/28/17 → 6/1/17

Bibliographical note

Publisher Copyright:
© The Electrochemical Society.

ASJC Scopus Subject Areas

General Engineering

Access to Document

10.1149/07711.0981ecst

Cite this

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title = "Incorporation of conductive internal additives within electrocuring adhesives",

abstract = "Aryl diazirine-grafted polyamidoamine (Dz-g-PAMAM) was recently investigated as an adhesive cured with low voltage potentials, leading to a concept of electrocuring adhesive. Ferrocene is a well-known redox active compound with a high degree of electron reversibility. Ferrocene is incorporated into the electrocuring adhesive as a conductive internal additive, attempting to improve the electron transfer efficiency. In this work, the synthesis of co-grafted Dz-g-Fc-g-PAMAM is confirmed by NMR and UV/Visible absorbance compares the optical properties with and without the ferrocene internal additive.",

author = "L. Gan and Tan, {N. C.S.} and Steele, {T. W.J.}",

note = "Publisher Copyright: {\textcopyright} The Electrochemical Society.; 231st ECS Meeting ; Conference date: 28-05-2017 Through 01-06-2017",

year = "2017",

doi = "10.1149/07711.0981ecst",

language = "English",

isbn = "9781623324605",

series = "ECS Transactions",

publisher = "Electrochemical Society Inc.",

number = "11",

pages = "981--988",

booktitle = "Selected Proceedings from the 231st ECS Meeting New Orleans, LA - Spring 2017",

edition = "11",

}

Gan, L, Tan, NCS & Steele, TWJ 2017, Incorporation of conductive internal additives within electrocuring adhesives. in Selected Proceedings from the 231st ECS Meeting New Orleans, LA - Spring 2017. 11 edn, ECS Transactions, no. 11, vol. 77, Electrochemical Society Inc., pp. 981-988, 231st ECS Meeting, New Orleans, United States, 5/28/17. https://doi.org/10.1149/07711.0981ecst

Incorporation of conductive internal additives within electrocuring adhesives. / Gan, L.; Tan, N. C.S.; Steele, T. W.J.
Selected Proceedings from the 231st ECS Meeting New Orleans, LA - Spring 2017. 11. ed. Electrochemical Society Inc., 2017. p. 981-988 (ECS Transactions; Vol. 77, No. 11).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

TY - GEN

T1 - Incorporation of conductive internal additives within electrocuring adhesives

AU - Gan, L.

AU - Tan, N. C.S.

AU - Steele, T. W.J.

PY - 2017

Y1 - 2017

N2 - Aryl diazirine-grafted polyamidoamine (Dz-g-PAMAM) was recently investigated as an adhesive cured with low voltage potentials, leading to a concept of electrocuring adhesive. Ferrocene is a well-known redox active compound with a high degree of electron reversibility. Ferrocene is incorporated into the electrocuring adhesive as a conductive internal additive, attempting to improve the electron transfer efficiency. In this work, the synthesis of co-grafted Dz-g-Fc-g-PAMAM is confirmed by NMR and UV/Visible absorbance compares the optical properties with and without the ferrocene internal additive.

AB - Aryl diazirine-grafted polyamidoamine (Dz-g-PAMAM) was recently investigated as an adhesive cured with low voltage potentials, leading to a concept of electrocuring adhesive. Ferrocene is a well-known redox active compound with a high degree of electron reversibility. Ferrocene is incorporated into the electrocuring adhesive as a conductive internal additive, attempting to improve the electron transfer efficiency. In this work, the synthesis of co-grafted Dz-g-Fc-g-PAMAM is confirmed by NMR and UV/Visible absorbance compares the optical properties with and without the ferrocene internal additive.

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M3 - Conference contribution

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SN - 9781623324605

T3 - ECS Transactions

SP - 981

EP - 988

BT - Selected Proceedings from the 231st ECS Meeting New Orleans, LA - Spring 2017

PB - Electrochemical Society Inc.

T2 - 231st ECS Meeting

Y2 - 28 May 2017 through 1 June 2017

ER -

Incorporation of conductive internal additives within electrocuring adhesives

Abstract

Publication series

Conference

Bibliographical note

ASJC Scopus Subject Areas

Access to Document

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