Iridafurans from the reaction of [CpIrCl2]2 with carbonyl conjugated terminal alkynes: Dependence of product on polarity of reaction medium

Kai Ning Wong; Kar Hang Garvin Mak; Wai Yip Fan; Venugopal Shanmugham Sridevi; Weng Kee Leong

doi:10.1016/j.jorganchem.2013.05.021

Iridafurans from the reaction of [CpIrCl2]2 with carbonyl conjugated terminal alkynes: Dependence of product on polarity of reaction medium

Kai Ning Wong, Kar Hang Garvin Mak, Wai Yip Fan^*, Venugopal Shanmugham Sridevi, Weng Kee Leong

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Reaction of the dimeric species [Cp IrCl₂]₂ with terminal alkynes containing a conjugated carbonyl group results in CeC bond formation between two or three alkyne molecules, depending on the polarity of the reaction medium. The reaction pathway has been studied experimentally and computationally.

Original language	English
Pages (from-to)	40-46
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	741-742
Issue number	1
DOIs	https://doi.org/10.1016/j.jorganchem.2013.05.021
Publication status	Published - 2013
Externally published	Yes

ASJC Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Keywords

CeC coupling
Conjugated carbonyl
Iridafuran
Iridium
Terminal alkyne

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10.1016/j.jorganchem.2013.05.021

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title = "Iridafurans from the reaction of [CpIrCl2]2 with carbonyl conjugated terminal alkynes: Dependence of product on polarity of reaction medium",

abstract = "Reaction of the dimeric species [Cp IrCl2]2 with terminal alkynes containing a conjugated carbonyl group results in CeC bond formation between two or three alkyne molecules, depending on the polarity of the reaction medium. The reaction pathway has been studied experimentally and computationally.",

keywords = "CeC coupling, Conjugated carbonyl, Iridafuran, Iridium, Terminal alkyne",

author = "{Ning Wong}, Kai and Mak, {Kar Hang Garvin} and Fan, {Wai Yip} and Sridevi, {Venugopal Shanmugham} and Leong, {Weng Kee}",

year = "2013",

doi = "10.1016/j.jorganchem.2013.05.021",

language = "English",

volume = "741-742",

pages = "40--46",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "1",

}

TY - JOUR

T1 - Iridafurans from the reaction of [CpIrCl2]2 with carbonyl conjugated terminal alkynes

T2 - Dependence of product on polarity of reaction medium

AU - Ning Wong, Kai

AU - Mak, Kar Hang Garvin

AU - Fan, Wai Yip

AU - Sridevi, Venugopal Shanmugham

AU - Leong, Weng Kee

PY - 2013

Y1 - 2013

N2 - Reaction of the dimeric species [Cp IrCl2]2 with terminal alkynes containing a conjugated carbonyl group results in CeC bond formation between two or three alkyne molecules, depending on the polarity of the reaction medium. The reaction pathway has been studied experimentally and computationally.

AB - Reaction of the dimeric species [Cp IrCl2]2 with terminal alkynes containing a conjugated carbonyl group results in CeC bond formation between two or three alkyne molecules, depending on the polarity of the reaction medium. The reaction pathway has been studied experimentally and computationally.

KW - CeC coupling

KW - Conjugated carbonyl

KW - Iridafuran

KW - Iridium

KW - Terminal alkyne

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UR - http://www.scopus.com/inward/citedby.url?scp=84884492860&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2013.05.021

DO - 10.1016/j.jorganchem.2013.05.021

M3 - Article

AN - SCOPUS:84884492860

SN - 0022-328X

VL - 741-742

SP - 40

EP - 46

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Iridafurans from the reaction of [CpIrCl2]2 with carbonyl conjugated terminal alkynes: Dependence of product on polarity of reaction medium

Abstract

ASJC Scopus Subject Areas

Keywords

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