Iron(III) chloride-promoted isomerization of propargyl alcohols to α,β-unsaturated carbonyl compounds

Ahmad Samih El Douhaibi; Zaher M.A. Judeh; Hedaya Basri; Ziad Moussa; Mouslim Messali; Gao Qi

doi:10.1080/00397911003611810

Iron(III) chloride-promoted isomerization of propargyl alcohols to α,β-unsaturated carbonyl compounds

Ahmad Samih El Douhaibi, Zaher M.A. Judeh, Hedaya Basri, Ziad Moussa, Mouslim Messali, Gao Qi

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Aryl propargyl alcohols bearing a terminal alkynyl moiety can undergo a facile iron(III) chloride-promoted transformation to the corresponding α,β-unsaturated aldehyde in good yield and excellent stereoselectivity.

Original language	English
Pages (from-to)	533-540
Number of pages	8
Journal	Synthetic Communications
Volume	41
Issue number	4
DOIs	https://doi.org/10.1080/00397911003611810
Publication status	Published - Jan 2011
Externally published	Yes

ASJC Scopus Subject Areas

Organic Chemistry

Keywords

Iron(III) chloride
isomerization
propargyl alcohols

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10.1080/00397911003611810

Cite this

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title = "Iron(III) chloride-promoted isomerization of propargyl alcohols to α,β-unsaturated carbonyl compounds",

abstract = "Aryl propargyl alcohols bearing a terminal alkynyl moiety can undergo a facile iron(III) chloride-promoted transformation to the corresponding α,β-unsaturated aldehyde in good yield and excellent stereoselectivity.",

keywords = "Iron(III) chloride, isomerization, propargyl alcohols",

author = "{El Douhaibi}, {Ahmad Samih} and Judeh, {Zaher M.A.} and Hedaya Basri and Ziad Moussa and Mouslim Messali and Gao Qi",

year = "2011",

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doi = "10.1080/00397911003611810",

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volume = "41",

pages = "533--540",

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T1 - Iron(III) chloride-promoted isomerization of propargyl alcohols to α,β-unsaturated carbonyl compounds

AU - El Douhaibi, Ahmad Samih

AU - Judeh, Zaher M.A.

AU - Basri, Hedaya

AU - Moussa, Ziad

AU - Messali, Mouslim

AU - Qi, Gao

PY - 2011/1

Y1 - 2011/1

N2 - Aryl propargyl alcohols bearing a terminal alkynyl moiety can undergo a facile iron(III) chloride-promoted transformation to the corresponding α,β-unsaturated aldehyde in good yield and excellent stereoselectivity.

AB - Aryl propargyl alcohols bearing a terminal alkynyl moiety can undergo a facile iron(III) chloride-promoted transformation to the corresponding α,β-unsaturated aldehyde in good yield and excellent stereoselectivity.

KW - Iron(III) chloride

KW - isomerization

KW - propargyl alcohols

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DO - 10.1080/00397911003611810

M3 - Article

AN - SCOPUS:79551656396

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VL - 41

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JF - Synthetic Communications

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ER -

Iron(III) chloride-promoted isomerization of propargyl alcohols to α,β-unsaturated carbonyl compounds

Abstract

ASJC Scopus Subject Areas

Keywords

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