Isolation and Reactivity of 1,4,2-Diazaborole

Bochao Su; Yongxin Li; Rakesh Ganguly; Jenny Lim; Rei Kinjo

doi:10.1021/jacs.5b07823

Isolation and Reactivity of 1,4,2-Diazaborole

Bochao Su, Yongxin Li, Rakesh Ganguly, Jenny Lim, Rei Kinjo^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

An isolable 1,4,2-diazaborole derivative was synthesized and structurally characterized. X-ray diffraction analysis and computational studies revealed a delocalization of 6π-electrons over the BC₂N₂ five-membered ring, which thus indicates the aromatic property. The reactivity toward electrophiles such as MeOTf and selectfluor was also investigated.

Original language	English
Pages (from-to)	11274-11277
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	137
Issue number	35
DOIs	https://doi.org/10.1021/jacs.5b07823
Publication status	Published - Sept 9 2015
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2015 American Chemical Society.

ASJC Scopus Subject Areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/jacs.5b07823

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abstract = "An isolable 1,4,2-diazaborole derivative was synthesized and structurally characterized. X-ray diffraction analysis and computational studies revealed a delocalization of 6π-electrons over the BC2N2 five-membered ring, which thus indicates the aromatic property. The reactivity toward electrophiles such as MeOTf and selectfluor was also investigated.",

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AU - Su, Bochao

AU - Li, Yongxin

AU - Ganguly, Rakesh

AU - Lim, Jenny

AU - Kinjo, Rei

PY - 2015/9/9

Y1 - 2015/9/9

N2 - An isolable 1,4,2-diazaborole derivative was synthesized and structurally characterized. X-ray diffraction analysis and computational studies revealed a delocalization of 6π-electrons over the BC2N2 five-membered ring, which thus indicates the aromatic property. The reactivity toward electrophiles such as MeOTf and selectfluor was also investigated.

AB - An isolable 1,4,2-diazaborole derivative was synthesized and structurally characterized. X-ray diffraction analysis and computational studies revealed a delocalization of 6π-electrons over the BC2N2 five-membered ring, which thus indicates the aromatic property. The reactivity toward electrophiles such as MeOTf and selectfluor was also investigated.

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Isolation and Reactivity of 1,4,2-Diazaborole

Abstract

Bibliographical note

ASJC Scopus Subject Areas

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