Isomers in the phosphine-substituted heteronuclear cluster RuOs3(µ-H)2(CO)12(PPh3) – A re-examination

Shi Hoe Ng; Weng Kee Leong

doi:10.1016/j.ica.2020.119989

Isomers in the phosphine-substituted heteronuclear cluster RuOs₃(µ-H)₂(CO)₁₂(PPh₃) – A re-examination

Shi Hoe Ng, Weng Kee Leong^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

Abstract

The solution-state isomers of the heteronuclear cluster RuOs₃(µ-H)₂(CO)₁₂(PPh₃) have been re-examined in the light of conflicting structural assignments for a closely-related analogue. The result is a reassignment of the structures and hence the exchange processes observed in the NMR spectra.

Original language	English
Article number	119989
Journal	Inorganica Chimica Acta
Volume	514
DOIs	https://doi.org/10.1016/j.ica.2020.119989
Publication status	Published - Jan 1 2021
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2020 Elsevier B.V.

ASJC Scopus Subject Areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Keywords

Carbonyl cluster
Isomers
Osmium
Phosphine
Ruthenium

Access to Document

10.1016/j.ica.2020.119989

Cite this

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abstract = "The solution-state isomers of the heteronuclear cluster RuOs3(µ-H)2(CO)12(PPh3) have been re-examined in the light of conflicting structural assignments for a closely-related analogue. The result is a reassignment of the structures and hence the exchange processes observed in the NMR spectra.",

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