Leveraging of Sulfur Anions in Photoinduced Molecular Transformations

Haoyu Li; Yuliang Liu; Shunsuke Chiba

doi:10.1021/jacsau.1c00363

Leveraging of Sulfur Anions in Photoinduced Molecular Transformations

Haoyu Li, Yuliang Liu, Shunsuke Chiba^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Review article › peer-review

51 Citations (Scopus)

Abstract

This perspective describes recent advances in the use of sulfur anions to promote molecular transformations under irradiation with visible light. The topics are classified by the following reaction modes performed by the key sulfur anions: (1) C-S coupling via electron donor-acceptor (EDA) interactions, (2) photoinduced molecular transformation via sulfur anion EDA catalysis, (3) sulfur anions as photoredox and hydrogen atom transfer (HAT) catalysts, and 4) dithiocarbamate and xanthate as nucleophilic catalysts for photoinduced radical cascade reactions.

Original language	English
Pages (from-to)	2121-2129
Number of pages	9
Journal	JACS Au
Volume	1
Issue number	12
DOIs	https://doi.org/10.1021/jacsau.1c00363
Publication status	Published - Dec 27 2021
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2021 American Chemical Society. All rights reserved.

ASJC Scopus Subject Areas

Analytical Chemistry
Chemistry (miscellaneous)
Physical and Theoretical Chemistry
Organic Chemistry

Keywords

Electron donor-acceptor interaction
Hydrogen atom transfer
Photocatalysis
Single-electron transfer
Sulfur anions

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10.1021/jacsau.1c00363

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title = "Leveraging of Sulfur Anions in Photoinduced Molecular Transformations",

abstract = "This perspective describes recent advances in the use of sulfur anions to promote molecular transformations under irradiation with visible light. The topics are classified by the following reaction modes performed by the key sulfur anions: (1) C-S coupling via electron donor-acceptor (EDA) interactions, (2) photoinduced molecular transformation via sulfur anion EDA catalysis, (3) sulfur anions as photoredox and hydrogen atom transfer (HAT) catalysts, and 4) dithiocarbamate and xanthate as nucleophilic catalysts for photoinduced radical cascade reactions.",

keywords = "Electron donor-acceptor interaction, Hydrogen atom transfer, Photocatalysis, Single-electron transfer, Sulfur anions",

author = "Haoyu Li and Yuliang Liu and Shunsuke Chiba",

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doi = "10.1021/jacsau.1c00363",

language = "English",

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T1 - Leveraging of Sulfur Anions in Photoinduced Molecular Transformations

AU - Li, Haoyu

AU - Liu, Yuliang

AU - Chiba, Shunsuke

PY - 2021/12/27

Y1 - 2021/12/27

N2 - This perspective describes recent advances in the use of sulfur anions to promote molecular transformations under irradiation with visible light. The topics are classified by the following reaction modes performed by the key sulfur anions: (1) C-S coupling via electron donor-acceptor (EDA) interactions, (2) photoinduced molecular transformation via sulfur anion EDA catalysis, (3) sulfur anions as photoredox and hydrogen atom transfer (HAT) catalysts, and 4) dithiocarbamate and xanthate as nucleophilic catalysts for photoinduced radical cascade reactions.

AB - This perspective describes recent advances in the use of sulfur anions to promote molecular transformations under irradiation with visible light. The topics are classified by the following reaction modes performed by the key sulfur anions: (1) C-S coupling via electron donor-acceptor (EDA) interactions, (2) photoinduced molecular transformation via sulfur anion EDA catalysis, (3) sulfur anions as photoredox and hydrogen atom transfer (HAT) catalysts, and 4) dithiocarbamate and xanthate as nucleophilic catalysts for photoinduced radical cascade reactions.

KW - Electron donor-acceptor interaction

KW - Hydrogen atom transfer

KW - Photocatalysis

KW - Single-electron transfer

KW - Sulfur anions

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DO - 10.1021/jacsau.1c00363

M3 - Review article

AN - SCOPUS:85127293974

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VL - 1

SP - 2121

EP - 2129

JO - JACS Au

JF - JACS Au

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ER -

Leveraging of Sulfur Anions in Photoinduced Molecular Transformations

Abstract

Bibliographical note

ASJC Scopus Subject Areas

Keywords

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