Macromolecular architectures designed by living radical polymerization with organic catalysts

Miho Tanishima; Atsushi Goto; Lin Lei; Akimichi Ohtsuki; Hironori Kaji; Akihiro Nomura; Yoshinobu Tsujii; Yu Yamaguchi; Hiroto Komatsu; Michihiko Miyamoto

doi:10.3390/polym6020311

Macromolecular architectures designed by living radical polymerization with organic catalysts

Miho Tanishima, Atsushi Goto^*, Lin Lei, Akimichi Ohtsuki, Hironori Kaji, Akihiro Nomura, Yoshinobu Tsujii, Yu Yamaguchi, Hiroto Komatsu, Michihiko Miyamoto

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

Well-defined diblock and triblock copolymers, star polymers, and concentrated polymer brushes on solid surfaces were prepared using living radical polymerization with organic catalysts. Polymerizations of methyl methacrylate, butyl acrylate, and selected functional methacrylates were performed with a monofunctional initiator, a difunctional initiator, a trifunctional initiator, and a surface-immobilized initiator.

Original language	English
Pages (from-to)	311-326
Number of pages	16
Journal	Polymers
Volume	6
Issue number	1
DOIs	https://doi.org/10.3390/polym6020311
Publication status	Published - 2014
Externally published	Yes

ASJC Scopus Subject Areas

General Chemistry
Polymers and Plastics

Keywords

Block copolymers
Living radical polymerization
Organic catalysts
Polymer brushes
Star polymers
Triblock copolymers

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10.3390/polym6020311

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title = "Macromolecular architectures designed by living radical polymerization with organic catalysts",

abstract = "Well-defined diblock and triblock copolymers, star polymers, and concentrated polymer brushes on solid surfaces were prepared using living radical polymerization with organic catalysts. Polymerizations of methyl methacrylate, butyl acrylate, and selected functional methacrylates were performed with a monofunctional initiator, a difunctional initiator, a trifunctional initiator, and a surface-immobilized initiator.",

keywords = "Block copolymers, Living radical polymerization, Organic catalysts, Polymer brushes, Star polymers, Triblock copolymers",

author = "Miho Tanishima and Atsushi Goto and Lin Lei and Akimichi Ohtsuki and Hironori Kaji and Akihiro Nomura and Yoshinobu Tsujii and Yu Yamaguchi and Hiroto Komatsu and Michihiko Miyamoto",

year = "2014",

doi = "10.3390/polym6020311",

language = "English",

volume = "6",

pages = "311--326",

journal = "Polymers",

issn = "2073-4360",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

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TY - JOUR

T1 - Macromolecular architectures designed by living radical polymerization with organic catalysts

AU - Tanishima, Miho

AU - Goto, Atsushi

AU - Lei, Lin

AU - Ohtsuki, Akimichi

AU - Kaji, Hironori

AU - Nomura, Akihiro

AU - Tsujii, Yoshinobu

AU - Yamaguchi, Yu

AU - Komatsu, Hiroto

AU - Miyamoto, Michihiko

PY - 2014

Y1 - 2014

N2 - Well-defined diblock and triblock copolymers, star polymers, and concentrated polymer brushes on solid surfaces were prepared using living radical polymerization with organic catalysts. Polymerizations of methyl methacrylate, butyl acrylate, and selected functional methacrylates were performed with a monofunctional initiator, a difunctional initiator, a trifunctional initiator, and a surface-immobilized initiator.

AB - Well-defined diblock and triblock copolymers, star polymers, and concentrated polymer brushes on solid surfaces were prepared using living radical polymerization with organic catalysts. Polymerizations of methyl methacrylate, butyl acrylate, and selected functional methacrylates were performed with a monofunctional initiator, a difunctional initiator, a trifunctional initiator, and a surface-immobilized initiator.

KW - Block copolymers

KW - Living radical polymerization

KW - Organic catalysts

KW - Polymer brushes

KW - Star polymers

KW - Triblock copolymers

UR - http://www.scopus.com/inward/record.url?scp=84894092382&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84894092382&partnerID=8YFLogxK

U2 - 10.3390/polym6020311

DO - 10.3390/polym6020311

M3 - Article

AN - SCOPUS:84894092382

SN - 2073-4360

VL - 6

SP - 311

EP - 326

JO - Polymers

JF - Polymers

IS - 1

ER -

Macromolecular architectures designed by living radical polymerization with organic catalysts

Abstract

ASJC Scopus Subject Areas

Keywords

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