TY - GEN
T1 - Mechanisms and kinetics of living radical polymerization
T2 - absolute comparison of theory and experiment
AU - Fukuda, Takeshi
AU - Yoshikawa, Chiaki
AU - Kwak, Yungwan
AU - Goto, Atsushi
AU - Tsujii, Yoshinobu
PY - 2003
Y1 - 2003
N2 - Theories that have been proposed to describe the polymerization rates and polydispersities in living radical polymerization (LRP) were experimentally tested for main branches of LRP including nitroxide-mediated polymerization (NMP), atom transfer radical polymerization (ATRP), iodidemediated polymerization, and reversible additionfragmentation chain transfer (RAFT) polymerization. The theories were verified on an absolute scale in both the absence and presence of conventional initiation. The cause for the marked retardation in polymerization rate observed in a dithiobenzoate-mediated RAFT polymerization of styrene was eluciated.
AB - Theories that have been proposed to describe the polymerization rates and polydispersities in living radical polymerization (LRP) were experimentally tested for main branches of LRP including nitroxide-mediated polymerization (NMP), atom transfer radical polymerization (ATRP), iodidemediated polymerization, and reversible additionfragmentation chain transfer (RAFT) polymerization. The theories were verified on an absolute scale in both the absence and presence of conventional initiation. The cause for the marked retardation in polymerization rate observed in a dithiobenzoate-mediated RAFT polymerization of styrene was eluciated.
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U2 - 10.1021/bk-2003-0854.ch003
DO - 10.1021/bk-2003-0854.ch003
M3 - Conference contribution
AN - SCOPUS:49249121958
SN - 9780841238541
T3 - ACS Symposium Series
SP - 24
EP - 39
BT - Advances in Controlled/Living Radical Polymerization
PB - American Chemical Society
ER -