Mild Rh(III)-catalyzed direct C-H bond arylation of (hetero)arenes with arylsilanes in aqueous media

Ming Zhu Lu; Ping Lu; Yun He Xu; Teck Peng Loh

doi:10.1021/ol500754h

Mild Rh(III)-catalyzed direct C-H bond arylation of (hetero)arenes with arylsilanes in aqueous media

Ming Zhu Lu, Ping Lu, Yun He Xu^*, Teck Peng Loh

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

127 Citations (Scopus)

Abstract

An efficient rhodium(III)-catalyzed C-H bond activation and further direct arylation of (hetero)arenes with organosilanes in aqueous media was developed. This reaction shows good substrate scope and excellent functional group compatibility and gives the products in good yields with excellent regioselectivity.

Original language	English
Pages (from-to)	2614-2617
Number of pages	4
Journal	Organic Letters
Volume	16
Issue number	10
DOIs	https://doi.org/10.1021/ol500754h
Publication status	Published - May 16 2014
Externally published	Yes

ASJC Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol500754h

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title = "Mild Rh(III)-catalyzed direct C-H bond arylation of (hetero)arenes with arylsilanes in aqueous media",

abstract = "An efficient rhodium(III)-catalyzed C-H bond activation and further direct arylation of (hetero)arenes with organosilanes in aqueous media was developed. This reaction shows good substrate scope and excellent functional group compatibility and gives the products in good yields with excellent regioselectivity.",

author = "Lu, {Ming Zhu} and Ping Lu and Xu, {Yun He} and Loh, {Teck Peng}",

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AU - Lu, Ming Zhu

AU - Lu, Ping

AU - Xu, Yun He

AU - Loh, Teck Peng

PY - 2014/5/16

Y1 - 2014/5/16

N2 - An efficient rhodium(III)-catalyzed C-H bond activation and further direct arylation of (hetero)arenes with organosilanes in aqueous media was developed. This reaction shows good substrate scope and excellent functional group compatibility and gives the products in good yields with excellent regioselectivity.

AB - An efficient rhodium(III)-catalyzed C-H bond activation and further direct arylation of (hetero)arenes with organosilanes in aqueous media was developed. This reaction shows good substrate scope and excellent functional group compatibility and gives the products in good yields with excellent regioselectivity.

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Mild Rh(III)-catalyzed direct C-H bond arylation of (hetero)arenes with arylsilanes in aqueous media

Abstract

ASJC Scopus Subject Areas

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