Miscibility and interactions in blends and complexes of poly(4-methyl-5-vinylthiazole) with proton-donating polymers

X. F. Luo; X. Hu; X. Y. Zhao; S. H. Goh; X. D. Li

doi:10.1016/S0032-3861(03)00578-0

Miscibility and interactions in blends and complexes of poly(4-methyl-5-vinylthiazole) with proton-donating polymers

X. F. Luo, X. Hu^*, X. Y. Zhao, S. H. Goh, X. D. Li

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

The miscibility and interactions in blends and complexes of poly(4-methyl-5-vinylthiazole) (PMVT) with poly(p-vinylphenol) (PVPh), poly(acrylic acid) (PAA) and poly(vinylphosphonic acid) (PVPA) were studied. PMVT formed complexes with PVPA but not with PVPh and PAA. Each of the blends of PMVT with PVPh and PAA showed a single glass transition temperature (T _g), indicating miscibility. Fourier-transform infrared spectroscopic and X-ray photoelectron spectroscopic studies provided the existence of interactions in the PMVT blends and complexes. The XPS studies indicated that the thiazole nitrogen atoms are involved in hydrogen-bonding interactions with PVPh and PAA, and ionic interactions with PVPA. The sulfur atoms of PMVT also interact with PVPh, PAA and PVPA.

Original language	English
Pages (from-to)	5285-5291
Number of pages	7
Journal	Polymer
Volume	44
Issue number	18
DOIs	https://doi.org/10.1016/S0032-3861(03)00578-0
Publication status	Published - Aug 7 2003
Externally published	Yes

ASJC Scopus Subject Areas

Organic Chemistry
Polymers and Plastics
Materials Chemistry

Keywords

Interactions
Miscibility
Poly(4-methyl-5-vinylthiazole)

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10.1016/S0032-3861(03)00578-0

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title = "Miscibility and interactions in blends and complexes of poly(4-methyl-5-vinylthiazole) with proton-donating polymers",

abstract = "The miscibility and interactions in blends and complexes of poly(4-methyl-5-vinylthiazole) (PMVT) with poly(p-vinylphenol) (PVPh), poly(acrylic acid) (PAA) and poly(vinylphosphonic acid) (PVPA) were studied. PMVT formed complexes with PVPA but not with PVPh and PAA. Each of the blends of PMVT with PVPh and PAA showed a single glass transition temperature (T g), indicating miscibility. Fourier-transform infrared spectroscopic and X-ray photoelectron spectroscopic studies provided the existence of interactions in the PMVT blends and complexes. The XPS studies indicated that the thiazole nitrogen atoms are involved in hydrogen-bonding interactions with PVPh and PAA, and ionic interactions with PVPA. The sulfur atoms of PMVT also interact with PVPh, PAA and PVPA.",

keywords = "Interactions, Miscibility, Poly(4-methyl-5-vinylthiazole)",

author = "Luo, {X. F.} and X. Hu and Zhao, {X. Y.} and Goh, {S. H.} and Li, {X. D.}",

year = "2003",

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doi = "10.1016/S0032-3861(03)00578-0",

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T1 - Miscibility and interactions in blends and complexes of poly(4-methyl-5-vinylthiazole) with proton-donating polymers

AU - Luo, X. F.

AU - Hu, X.

AU - Zhao, X. Y.

AU - Goh, S. H.

AU - Li, X. D.

PY - 2003/8/7

Y1 - 2003/8/7

N2 - The miscibility and interactions in blends and complexes of poly(4-methyl-5-vinylthiazole) (PMVT) with poly(p-vinylphenol) (PVPh), poly(acrylic acid) (PAA) and poly(vinylphosphonic acid) (PVPA) were studied. PMVT formed complexes with PVPA but not with PVPh and PAA. Each of the blends of PMVT with PVPh and PAA showed a single glass transition temperature (T g), indicating miscibility. Fourier-transform infrared spectroscopic and X-ray photoelectron spectroscopic studies provided the existence of interactions in the PMVT blends and complexes. The XPS studies indicated that the thiazole nitrogen atoms are involved in hydrogen-bonding interactions with PVPh and PAA, and ionic interactions with PVPA. The sulfur atoms of PMVT also interact with PVPh, PAA and PVPA.

AB - The miscibility and interactions in blends and complexes of poly(4-methyl-5-vinylthiazole) (PMVT) with poly(p-vinylphenol) (PVPh), poly(acrylic acid) (PAA) and poly(vinylphosphonic acid) (PVPA) were studied. PMVT formed complexes with PVPA but not with PVPh and PAA. Each of the blends of PMVT with PVPh and PAA showed a single glass transition temperature (T g), indicating miscibility. Fourier-transform infrared spectroscopic and X-ray photoelectron spectroscopic studies provided the existence of interactions in the PMVT blends and complexes. The XPS studies indicated that the thiazole nitrogen atoms are involved in hydrogen-bonding interactions with PVPh and PAA, and ionic interactions with PVPA. The sulfur atoms of PMVT also interact with PVPh, PAA and PVPA.

KW - Interactions

KW - Miscibility

KW - Poly(4-methyl-5-vinylthiazole)

UR - http://www.scopus.com/inward/record.url?scp=0041528305&partnerID=8YFLogxK

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U2 - 10.1016/S0032-3861(03)00578-0

DO - 10.1016/S0032-3861(03)00578-0

M3 - Article

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SN - 0032-3861

VL - 44

SP - 5285

EP - 5291

JO - Polymer

JF - Polymer

IS - 18

ER -

Miscibility and interactions in blends and complexes of poly(4-methyl-5-vinylthiazole) with proton-donating polymers

Abstract

ASJC Scopus Subject Areas

Keywords

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