Modular access to triarylethylene units from arylvinyl MIDA boronates using a regioselective heck coupling

R. N. Khanizeman; E. Barde; R. W. Bates; A. Guérinot; J. Cossy

doi:10.1021/acs.orglett.7b02218

Modular access to triarylethylene units from arylvinyl MIDA boronates using a regioselective heck coupling

R. N. Khanizeman, E. Barde, R. W. Bates, A. Guérinot^*, J. Cossy

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

A palladium-catalyzed, silver-mediated Heck coupling between arylvinyl MIDA boronate esters and aryl iodides is disclosed. The reaction provides an efficient and modular access to a range of 1,1-diaryl alkenyl MIDA boronates that can be easily transformed into triarylethylene compounds through a Suzuki coupling.

Original language	English
Pages (from-to)	5046-5049
Number of pages	4
Journal	Organic Letters
Volume	19
Issue number	19
DOIs	https://doi.org/10.1021/acs.orglett.7b02218
Publication status	Published - Oct 6 2017
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2017 American Chemical Society.

ASJC Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/acs.orglett.7b02218

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abstract = "A palladium-catalyzed, silver-mediated Heck coupling between arylvinyl MIDA boronate esters and aryl iodides is disclosed. The reaction provides an efficient and modular access to a range of 1,1-diaryl alkenyl MIDA boronates that can be easily transformed into triarylethylene compounds through a Suzuki coupling.",

author = "Khanizeman, {R. N.} and E. Barde and Bates, {R. W.} and A. Gu{\'e}rinot and J. Cossy",

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T1 - Modular access to triarylethylene units from arylvinyl MIDA boronates using a regioselective heck coupling

AU - Khanizeman, R. N.

AU - Barde, E.

AU - Bates, R. W.

AU - Guérinot, A.

AU - Cossy, J.

PY - 2017/10/6

Y1 - 2017/10/6

N2 - A palladium-catalyzed, silver-mediated Heck coupling between arylvinyl MIDA boronate esters and aryl iodides is disclosed. The reaction provides an efficient and modular access to a range of 1,1-diaryl alkenyl MIDA boronates that can be easily transformed into triarylethylene compounds through a Suzuki coupling.

AB - A palladium-catalyzed, silver-mediated Heck coupling between arylvinyl MIDA boronate esters and aryl iodides is disclosed. The reaction provides an efficient and modular access to a range of 1,1-diaryl alkenyl MIDA boronates that can be easily transformed into triarylethylene compounds through a Suzuki coupling.

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Modular access to triarylethylene units from arylvinyl MIDA boronates using a regioselective heck coupling

Abstract

Bibliographical note

ASJC Scopus Subject Areas

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