N-Heterocyclic Carbene-Catalyzed Remote Enantioselective C-C Bond Formation via 1,6-Addition with Formyl Enynes

Keyphrases

• 1,6-addition 100%
• 1,6-Conjugate Addition 33%
• Addition Reaction 33%
• Axially chiral 33%
• Binding Position 33%
• Carbene Catalysis 33%
• Central-to-axial chirality Transfer 33%
• Chirality Control 33%
• Enynes 100%
• Nucleophile 33%
• Pyran 33%
• Pyrano 66%
• Pyrazole Derivatives 33%
• Reaction Sites 33%
• Stereogenic Centers 33%

Chemistry

• Enyne 100%
• Lowest Unoccupied Molecular Orbital 25%
• Nucleophile 25%
• Pyran 25%
• Pyrazole 25%