N-Heterocyclic Carbene-Mediated Carbon-Sulfur Bond-Forming Reactions

Jie Lv; Zhichao Jin; Hongling Wang; Yonggui Robin Chi

doi:10.1021/acssuschemeng.2c03868

N-Heterocyclic Carbene-Mediated Carbon-Sulfur Bond-Forming Reactions

Jie Lv, Zhichao Jin, Hongling Wang^*, Yonggui Robin Chi^*

^*Corresponding author for this work

Research output: Contribution to journal › Review article › peer-review

9 Citations (Scopus)

Abstract

The carbon-sulfur (C-S) bond formation reactions enabled by N-heterocyclic carbene (NHC) organocatalysis are systematically summarized in this review. Diverse transformations involving NHC-catalyzed S-esterification, NHC-catalyzed nucleophilic S-conjugate addition, NHC-catalyzed S-addition reactions with electrophiles, and C-S bond formations via cooperative NHC/transition metal-catalyzed radical reactions are introduced and discussed. Our own comprehension and perspectives on this highly active research field are also provided at the end of this review.

Original language	English
Pages (from-to)	13901-13916
Number of pages	16
Journal	ACS Sustainable Chemistry and Engineering
Volume	10
Issue number	42
DOIs	https://doi.org/10.1021/acssuschemeng.2c03868
Publication status	Published - Oct 24 2022
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2022 American Chemical Society.

ASJC Scopus Subject Areas

General Chemistry
Environmental Chemistry
General Chemical Engineering
Renewable Energy, Sustainability and the Environment

Keywords

Carbon-Sulfur Bond Formation
N-Heterocyclic Carbene
Sulfa-Michael Addition
Thioesterification

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1021/acssuschemeng.2c03868

Cite this

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title = "N-Heterocyclic Carbene-Mediated Carbon-Sulfur Bond-Forming Reactions",

abstract = "The carbon-sulfur (C-S) bond formation reactions enabled by N-heterocyclic carbene (NHC) organocatalysis are systematically summarized in this review. Diverse transformations involving NHC-catalyzed S-esterification, NHC-catalyzed nucleophilic S-conjugate addition, NHC-catalyzed S-addition reactions with electrophiles, and C-S bond formations via cooperative NHC/transition metal-catalyzed radical reactions are introduced and discussed. Our own comprehension and perspectives on this highly active research field are also provided at the end of this review.",

keywords = "Carbon-Sulfur Bond Formation, N-Heterocyclic Carbene, Sulfa-Michael Addition, Thioesterification",

author = "Jie Lv and Zhichao Jin and Hongling Wang and Chi, {Yonggui Robin}",

note = "Publisher Copyright: {\textcopyright} 2022 American Chemical Society.",

year = "2022",

month = oct,

day = "24",

doi = "10.1021/acssuschemeng.2c03868",

language = "English",

volume = "10",

pages = "13901--13916",

journal = "ACS Sustainable Chemistry and Engineering",

issn = "2168-0485",

publisher = "American Chemical Society",

number = "42",

}

TY - JOUR

T1 - N-Heterocyclic Carbene-Mediated Carbon-Sulfur Bond-Forming Reactions

AU - Lv, Jie

AU - Jin, Zhichao

AU - Wang, Hongling

AU - Chi, Yonggui Robin

PY - 2022/10/24

Y1 - 2022/10/24

N2 - The carbon-sulfur (C-S) bond formation reactions enabled by N-heterocyclic carbene (NHC) organocatalysis are systematically summarized in this review. Diverse transformations involving NHC-catalyzed S-esterification, NHC-catalyzed nucleophilic S-conjugate addition, NHC-catalyzed S-addition reactions with electrophiles, and C-S bond formations via cooperative NHC/transition metal-catalyzed radical reactions are introduced and discussed. Our own comprehension and perspectives on this highly active research field are also provided at the end of this review.

AB - The carbon-sulfur (C-S) bond formation reactions enabled by N-heterocyclic carbene (NHC) organocatalysis are systematically summarized in this review. Diverse transformations involving NHC-catalyzed S-esterification, NHC-catalyzed nucleophilic S-conjugate addition, NHC-catalyzed S-addition reactions with electrophiles, and C-S bond formations via cooperative NHC/transition metal-catalyzed radical reactions are introduced and discussed. Our own comprehension and perspectives on this highly active research field are also provided at the end of this review.

KW - Carbon-Sulfur Bond Formation

KW - N-Heterocyclic Carbene

KW - Sulfa-Michael Addition

KW - Thioesterification

UR - http://www.scopus.com/inward/record.url?scp=85140861585&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85140861585&partnerID=8YFLogxK

U2 - 10.1021/acssuschemeng.2c03868

DO - 10.1021/acssuschemeng.2c03868

M3 - Review article

AN - SCOPUS:85140861585

SN - 2168-0485

VL - 10

SP - 13901

EP - 13916

JO - ACS Sustainable Chemistry and Engineering

JF - ACS Sustainable Chemistry and Engineering

IS - 42

ER -

N-Heterocyclic Carbene-Mediated Carbon-Sulfur Bond-Forming Reactions

Abstract

Bibliographical note

ASJC Scopus Subject Areas

Keywords

UN SDGs

Access to Document

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