Abstract
Nickel-catalyzed Heck reaction of cycloalkenes delivers unusual conjugated arylated isomers. Nickel(0) catalysts ligated by chelating dialkylphosphines effectively activate not only aryl triflates as electrophiles, but also less reactive aryl mesylates, tosylates and pivalates. The omission of bases allows nickel hydride species to exist long enough to performin situolefin isomerization of initial Heck adducts.
| Original language | English |
|---|---|
| Pages (from-to) | 3933-3936 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 57 |
| Issue number | 32 |
| DOIs | |
| Publication status | Published - Apr 25 2021 |
| Externally published | Yes |
Bibliographical note
Publisher Copyright:© The Royal Society of Chemistry 2021.
ASJC Scopus Subject Areas
- Electronic, Optical and Magnetic Materials
- Catalysis
- Ceramics and Composites
- General Chemistry
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry