Orthometalated amino-carbene derivatives of iridium via anilines and terminal alkynes

Elumalai Kumaran; Venugopal Shanmugham Sridevi; Weng Kee Leong

doi:10.1021/om100803g

Orthometalated amino-carbene derivatives of iridium via anilines and terminal alkynes

Elumalai Kumaran, Venugopal Shanmugham Sridevi, Weng Kee Leong

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

The reaction of a terminal alkyne (RCCH) and an aniline (R′C ₆H₄NH₂) with the dinuclear species [Cp*IrCl₂]₂ afforded cyclometalated amino-carbene derivatives Cp*Ir(Cl)[=C(CH₂R)NHC₆H ₃R′] via a hydroamination and an orthometalation. The reaction pathway has been examined through deuterium labeling and computational studies.

Original language	English
Pages (from-to)	6417-6421
Number of pages	5
Journal	Organometallics
Volume	29
Issue number	23
DOIs	https://doi.org/10.1021/om100803g
Publication status	Published - Dec 13 2010
Externally published	Yes

ASJC Scopus Subject Areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Orthometalated amino-carbene derivatives of iridium via anilines and terminal alkynes",

abstract = "The reaction of a terminal alkyne (RCCH) and an aniline (R′C 6H4NH2) with the dinuclear species [Cp*IrCl2]2 afforded cyclometalated amino-carbene derivatives Cp*Ir(Cl)[=C(CH2R)NHC6H 3R′] via a hydroamination and an orthometalation. The reaction pathway has been examined through deuterium labeling and computational studies.",

author = "Elumalai Kumaran and Sridevi, \{Venugopal Shanmugham\} and Leong, \{Weng Kee\}",

year = "2010",

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AU - Kumaran, Elumalai

AU - Sridevi, Venugopal Shanmugham

AU - Leong, Weng Kee

PY - 2010/12/13

Y1 - 2010/12/13

N2 - The reaction of a terminal alkyne (RCCH) and an aniline (R′C 6H4NH2) with the dinuclear species [Cp*IrCl2]2 afforded cyclometalated amino-carbene derivatives Cp*Ir(Cl)[=C(CH2R)NHC6H 3R′] via a hydroamination and an orthometalation. The reaction pathway has been examined through deuterium labeling and computational studies.

AB - The reaction of a terminal alkyne (RCCH) and an aniline (R′C 6H4NH2) with the dinuclear species [Cp*IrCl2]2 afforded cyclometalated amino-carbene derivatives Cp*Ir(Cl)[=C(CH2R)NHC6H 3R′] via a hydroamination and an orthometalation. The reaction pathway has been examined through deuterium labeling and computational studies.

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JF - Organometallics

IS - 23

ER -

Orthometalated amino-carbene derivatives of iridium via anilines and terminal alkynes

Abstract

ASJC Scopus Subject Areas

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