Os3(CO)11(BiPh3): The missing link in osmium-bismuth cluster chemistry

Suat Ping Oh; Ying Zhou Li; Weng Kee Leong

doi:10.1016/j.jorganchem.2015.02.005

Os₃(CO)₁₁(BiPh₃): The missing link in osmium-bismuth cluster chemistry

Suat Ping Oh, Ying Zhou Li, Weng Kee Leong^*

^*Corresponding author for this work

Research output: Contribution to journal › Short survey › peer-review

7 Citations (Scopus)

Abstract

Abstract The room temperature reaction of Os₃(CO)₁₁(NCCH₃) with BiPh₃ afforded the substituted derivative Os₃(CO)₁₁(BiPh₃) which decomposed rapidly. The X-ray crystallographic study is reported, together with that of the stibine and arsine analogues.

Original language	English
Article number	18905
Pages (from-to)	46-48
Number of pages	3
Journal	Journal of Organometallic Chemistry
Volume	783
DOIs	https://doi.org/10.1016/j.jorganchem.2015.02.005
Publication status	Published - Jun 1 2015
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2015 Elsevier B.V. All rights reserved.

ASJC Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Keywords

Bismuth
Carbonyl cluster
Osmium

Access to Document

10.1016/j.jorganchem.2015.02.005

Cite this

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title = "Os3(CO)11(BiPh3): The missing link in osmium-bismuth cluster chemistry",

abstract = "Abstract The room temperature reaction of Os3(CO)11(NCCH3) with BiPh3 afforded the substituted derivative Os3(CO)11(BiPh3) which decomposed rapidly. The X-ray crystallographic study is reported, together with that of the stibine and arsine analogues.",

keywords = "Bismuth, Carbonyl cluster, Osmium",

author = "Oh, {Suat Ping} and Li, {Ying Zhou} and Leong, {Weng Kee}",

year = "2015",

month = jun,

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doi = "10.1016/j.jorganchem.2015.02.005",

language = "English",

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journal = "Journal of Organometallic Chemistry",

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TY - JOUR

T1 - Os3(CO)11(BiPh3)

T2 - The missing link in osmium-bismuth cluster chemistry

AU - Oh, Suat Ping

AU - Li, Ying Zhou

AU - Leong, Weng Kee

PY - 2015/6/1

Y1 - 2015/6/1

N2 - Abstract The room temperature reaction of Os3(CO)11(NCCH3) with BiPh3 afforded the substituted derivative Os3(CO)11(BiPh3) which decomposed rapidly. The X-ray crystallographic study is reported, together with that of the stibine and arsine analogues.

AB - Abstract The room temperature reaction of Os3(CO)11(NCCH3) with BiPh3 afforded the substituted derivative Os3(CO)11(BiPh3) which decomposed rapidly. The X-ray crystallographic study is reported, together with that of the stibine and arsine analogues.

KW - Bismuth

KW - Carbonyl cluster

KW - Osmium

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U2 - 10.1016/j.jorganchem.2015.02.005

DO - 10.1016/j.jorganchem.2015.02.005

M3 - Short survey

AN - SCOPUS:84925131159

SN - 0022-328X

VL - 783

SP - 46

EP - 48

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

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