[Os5 (μ-H)2 (CO)16]: A second crystal form

Weng Kee Leong; Frederick W.B. Einstein; Roland K. Pomeroy

doi:10.1107/S0108270196000339

[O_s5 (μ-H)₂ (CO)₁₆]: A second crystal form

Weng Kee Leong^*, Frederick W.B. Einstein, Roland K. Pomeroy

^*Corresponding author for this work

Simon Fraser University

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The title compound, hexadecacarbonyl-1κ³C,2κ³C,-3κ ³C,4κ⁴C,5κ ³C-di-μ-hydrido-1:2κ²H;1:3κ ²H-pentaosmium(8 Os-Os), has been crystallized in a different crystal form from that reported previously [Guy & Sheldrick (1978). Acta Cryst. B34, 1725-1727]. The form reported here has crystallographic mirror symmetry and the packing arrangement in the crystal exhibits a different relative orientation of the molecules from the earlier structure.

Original language	English
Pages (from-to)	1607-1609
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	52
Issue number	7
DOIs	https://doi.org/10.1107/S0108270196000339
Publication status	Published - Jul 15 1996
Externally published	Yes

ASJC Scopus Subject Areas

General Biochemistry,Genetics and Molecular Biology

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title = "[Os5 (μ-H)2 (CO)16]: A second crystal form",

abstract = "The title compound, hexadecacarbonyl-1κ3C,2κ3C,-3κ 3C,4κ4C,5κ 3C-di-μ-hydrido-1:2κ2H;1:3κ 2H-pentaosmium(8 Os-Os), has been crystallized in a different crystal form from that reported previously [Guy & Sheldrick (1978). Acta Cryst. B34, 1725-1727]. The form reported here has crystallographic mirror symmetry and the packing arrangement in the crystal exhibits a different relative orientation of the molecules from the earlier structure.",

author = "Leong, {Weng Kee} and Einstein, {Frederick W.B.} and Pomeroy, {Roland K.}",

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T1 - [Os5 (μ-H)2 (CO)16]

T2 - A second crystal form

AU - Leong, Weng Kee

AU - Einstein, Frederick W.B.

AU - Pomeroy, Roland K.

PY - 1996/7/15

Y1 - 1996/7/15

N2 - The title compound, hexadecacarbonyl-1κ3C,2κ3C,-3κ 3C,4κ4C,5κ 3C-di-μ-hydrido-1:2κ2H;1:3κ 2H-pentaosmium(8 Os-Os), has been crystallized in a different crystal form from that reported previously [Guy & Sheldrick (1978). Acta Cryst. B34, 1725-1727]. The form reported here has crystallographic mirror symmetry and the packing arrangement in the crystal exhibits a different relative orientation of the molecules from the earlier structure.

AB - The title compound, hexadecacarbonyl-1κ3C,2κ3C,-3κ 3C,4κ4C,5κ 3C-di-μ-hydrido-1:2κ2H;1:3κ 2H-pentaosmium(8 Os-Os), has been crystallized in a different crystal form from that reported previously [Guy & Sheldrick (1978). Acta Cryst. B34, 1725-1727]. The form reported here has crystallographic mirror symmetry and the packing arrangement in the crystal exhibits a different relative orientation of the molecules from the earlier structure.

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[O_s5 (μ-H)₂ (CO)₁₆]: A second crystal form

Abstract

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