Overlooked calendar issues of aqueous zinc metal batteries

Bao Zhang, Hong Jin Fan*

*Corresponding author for this work

Research output: Contribution to journalReview articlepeer-review

5 Citations (Scopus)

Abstract

Although the zinc metal plating and stripping chemistry offers a high specific capacity, this process suffers from poor reversibility, a crucial factor for long-term energy storage. Most studies so far have been focusing on cyclic aging but overlooked the impact of calendar aging on zinc metal behavior. In this perspective, we highlight the nearly cycle-independent and time-linear calendar aging mode of zinc metal anodes due to the lack of a protective solid-electrolyte interphase (SEI). This calendar aging could be the dominant factor in battery degradation throughout the entire life cycle. We advocate for a more critical evaluation of the battery lifespan and suggest strategies to circumvent calendar aging.

Original languageEnglish
Article number101802
JournalJoule
Volume9
Issue number1
DOIs
Publication statusPublished - Jan 15 2025
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2024 Elsevier Inc.

ASJC Scopus Subject Areas

  • General Energy

Keywords

  • aqueous Zn battery for energy storage
  • Coulombic efficiency
  • dead zinc
  • electrolyte engineering
  • solid-electrolyte interphase
  • zinc anode protection
  • zinc dendrites and corrosion

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