Oxadiazabicyclooctenone as a versatile monomer for the construction of pH sensitive functional polymers: Via ROMP

Asadulla Mallick; Yuan Xu; Yichao Lin; Jingxi He; Mary B. Chan-Park; Xue Wei Liu

doi:10.1039/c7py01413a

Oxadiazabicyclooctenone as a versatile monomer for the construction of pH sensitive functional polymers: Via ROMP

Asadulla Mallick, Yuan Xu, Yichao Lin, Jingxi He, Mary B. Chan-Park^*, Xue Wei Liu

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Ring-opening metathesis polymerization (ROMP) is a powerful method for the synthesis of various functional polymers including, but not limited to, biologically active polymers owing to its living character. However, the majority of polymers obtained by ROMP have a nondegradable backbone and there are very few examples of fully degradable polymers synthesized via ROMP. Herein, oxadiazabicyclooctenone is successfully developed as a versatile monomer for the construction of new pH-sensitive polymers by ROMP. The degradability was also introduced into the backbone of poly(oxa)norbornenes by copolymerization.

Original language	English
Pages (from-to)	372-377
Number of pages	6
Journal	Polymer Chemistry
Volume	9
Issue number	3
DOIs	https://doi.org/10.1039/c7py01413a
Publication status	Published - Jan 21 2018
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2018 The Royal Society of Chemistry.

ASJC Scopus Subject Areas

Bioengineering
Biochemistry
Polymers and Plastics
Organic Chemistry

Access to Document

10.1039/c7py01413a

Cite this

@article{5fb89994ad024f17a69b02c55213e88b,

title = "Oxadiazabicyclooctenone as a versatile monomer for the construction of pH sensitive functional polymers: Via ROMP",

abstract = "Ring-opening metathesis polymerization (ROMP) is a powerful method for the synthesis of various functional polymers including, but not limited to, biologically active polymers owing to its living character. However, the majority of polymers obtained by ROMP have a nondegradable backbone and there are very few examples of fully degradable polymers synthesized via ROMP. Herein, oxadiazabicyclooctenone is successfully developed as a versatile monomer for the construction of new pH-sensitive polymers by ROMP. The degradability was also introduced into the backbone of poly(oxa)norbornenes by copolymerization.",

author = "Asadulla Mallick and Yuan Xu and Yichao Lin and Jingxi He and Chan-Park, {Mary B.} and Liu, {Xue Wei}",

note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",

year = "2018",

month = jan,

day = "21",

doi = "10.1039/c7py01413a",

language = "English",

volume = "9",

pages = "372--377",

journal = "Polymer Chemistry",

issn = "1759-9954",

publisher = "Royal Society of Chemistry",

number = "3",

}

TY - JOUR

T1 - Oxadiazabicyclooctenone as a versatile monomer for the construction of pH sensitive functional polymers

T2 - Via ROMP

AU - Mallick, Asadulla

AU - Xu, Yuan

AU - Lin, Yichao

AU - He, Jingxi

AU - Chan-Park, Mary B.

AU - Liu, Xue Wei

PY - 2018/1/21

Y1 - 2018/1/21

N2 - Ring-opening metathesis polymerization (ROMP) is a powerful method for the synthesis of various functional polymers including, but not limited to, biologically active polymers owing to its living character. However, the majority of polymers obtained by ROMP have a nondegradable backbone and there are very few examples of fully degradable polymers synthesized via ROMP. Herein, oxadiazabicyclooctenone is successfully developed as a versatile monomer for the construction of new pH-sensitive polymers by ROMP. The degradability was also introduced into the backbone of poly(oxa)norbornenes by copolymerization.

AB - Ring-opening metathesis polymerization (ROMP) is a powerful method for the synthesis of various functional polymers including, but not limited to, biologically active polymers owing to its living character. However, the majority of polymers obtained by ROMP have a nondegradable backbone and there are very few examples of fully degradable polymers synthesized via ROMP. Herein, oxadiazabicyclooctenone is successfully developed as a versatile monomer for the construction of new pH-sensitive polymers by ROMP. The degradability was also introduced into the backbone of poly(oxa)norbornenes by copolymerization.

UR - http://www.scopus.com/inward/record.url?scp=85040814329&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85040814329&partnerID=8YFLogxK

U2 - 10.1039/c7py01413a

DO - 10.1039/c7py01413a

M3 - Article

AN - SCOPUS:85040814329

SN - 1759-9954

VL - 9

SP - 372

EP - 377

JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 3

ER -

Oxadiazabicyclooctenone as a versatile monomer for the construction of pH sensitive functional polymers: Via ROMP

Abstract

Bibliographical note

ASJC Scopus Subject Areas

Access to Document

Other files and links

Fingerprint

Cite this