Oxidant-free Rh(III)-catalyzed direct C-H olefination of arenes with allyl acetates

Chao Feng; Daming Feng; Teck Peng Loh

doi:10.1021/ol4015442

Oxidant-free Rh(III)-catalyzed direct C-H olefination of arenes with allyl acetates

Chao Feng, Daming Feng, Teck Peng Loh^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

105 Citations (Scopus)

Abstract

Rh(III)-catalyzed direct olefination of arenes with allyl acetate via C-H bond activation is described using N,N-disubstituted aminocarbonyl as the directing group. The catalyst undergoes a redox neutral process, and high to excellent yields of trans-products are obtained. This protocol exhibits a wide spectrum of functionality compatibility because of the simple reaction conditions employed and provides a highly effective synthetic method in the realm of C-H olefination.

Original language	English
Pages (from-to)	3670-3673
Number of pages	4
Journal	Organic Letters
Volume	15
Issue number	14
DOIs	https://doi.org/10.1021/ol4015442
Publication status	Published - Jul 19 2013
Externally published	Yes

ASJC Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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abstract = "Rh(III)-catalyzed direct olefination of arenes with allyl acetate via C-H bond activation is described using N,N-disubstituted aminocarbonyl as the directing group. The catalyst undergoes a redox neutral process, and high to excellent yields of trans-products are obtained. This protocol exhibits a wide spectrum of functionality compatibility because of the simple reaction conditions employed and provides a highly effective synthetic method in the realm of C-H olefination.",

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AU - Feng, Daming

AU - Loh, Teck Peng

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Y1 - 2013/7/19

N2 - Rh(III)-catalyzed direct olefination of arenes with allyl acetate via C-H bond activation is described using N,N-disubstituted aminocarbonyl as the directing group. The catalyst undergoes a redox neutral process, and high to excellent yields of trans-products are obtained. This protocol exhibits a wide spectrum of functionality compatibility because of the simple reaction conditions employed and provides a highly effective synthetic method in the realm of C-H olefination.

AB - Rh(III)-catalyzed direct olefination of arenes with allyl acetate via C-H bond activation is described using N,N-disubstituted aminocarbonyl as the directing group. The catalyst undergoes a redox neutral process, and high to excellent yields of trans-products are obtained. This protocol exhibits a wide spectrum of functionality compatibility because of the simple reaction conditions employed and provides a highly effective synthetic method in the realm of C-H olefination.

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JO - Organic Letters

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Oxidant-free Rh(III)-catalyzed direct C-H olefination of arenes with allyl acetates

Abstract

ASJC Scopus Subject Areas

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