Oxidative addition of elemental selenium to 1,4,2,5-diazadiborinine

Gillian Kor Hwee Goh; Yongxin Li; Rei Kinjo

doi:10.1039/c9dt01081e

Oxidative addition of elemental selenium to 1,4,2,5-diazadiborinine

Gillian Kor Hwee Goh, Yongxin Li, Rei Kinjo^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Annulated 1,4,2,5-diazadiborinine 3 has been synthesized and fully characterized. Computational studies revealed that compound 3 features a relatively small HOMO-LUMO gap (2.61 eV). When 3 was treated with elemental grey selenium (Se), oxidative addition of Se proceeded regioselectively at the boron centres of 3 to give a bicyclo[2.2.2] molecule 4 involving a B-Se-Se-B unit, which can be deemed a heavier analogue of dibora-peroxide.

Original language	English
Pages (from-to)	7514-7518
Number of pages	5
Journal	Dalton Transactions
Volume	48
Issue number	22
DOIs	https://doi.org/10.1039/c9dt01081e
Publication status	Published - 2019
Externally published	Yes

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Publisher Copyright:
© 2019 The Royal Society of Chemistry.

ASJC Scopus Subject Areas

Inorganic Chemistry

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title = "Oxidative addition of elemental selenium to 1,4,2,5-diazadiborinine",

abstract = "Annulated 1,4,2,5-diazadiborinine 3 has been synthesized and fully characterized. Computational studies revealed that compound 3 features a relatively small HOMO-LUMO gap (2.61 eV). When 3 was treated with elemental grey selenium (Se), oxidative addition of Se proceeded regioselectively at the boron centres of 3 to give a bicyclo[2.2.2] molecule 4 involving a B-Se-Se-B unit, which can be deemed a heavier analogue of dibora-peroxide.",

author = "Goh, {Gillian Kor Hwee} and Yongxin Li and Rei Kinjo",

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AU - Goh, Gillian Kor Hwee

AU - Li, Yongxin

AU - Kinjo, Rei

PY - 2019

Y1 - 2019

N2 - Annulated 1,4,2,5-diazadiborinine 3 has been synthesized and fully characterized. Computational studies revealed that compound 3 features a relatively small HOMO-LUMO gap (2.61 eV). When 3 was treated with elemental grey selenium (Se), oxidative addition of Se proceeded regioselectively at the boron centres of 3 to give a bicyclo[2.2.2] molecule 4 involving a B-Se-Se-B unit, which can be deemed a heavier analogue of dibora-peroxide.

AB - Annulated 1,4,2,5-diazadiborinine 3 has been synthesized and fully characterized. Computational studies revealed that compound 3 features a relatively small HOMO-LUMO gap (2.61 eV). When 3 was treated with elemental grey selenium (Se), oxidative addition of Se proceeded regioselectively at the boron centres of 3 to give a bicyclo[2.2.2] molecule 4 involving a B-Se-Se-B unit, which can be deemed a heavier analogue of dibora-peroxide.

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Oxidative addition of elemental selenium to 1,4,2,5-diazadiborinine

Abstract

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ASJC Scopus Subject Areas

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