Oxidative addition of halogen across an Os-Os or Os-Sb bond: Formation of five-membered osmium-antimony carbonyl rings

Ying Zhou Li; Rakesh Ganguly; Weng Kee Leong

doi:10.1016/j.jorganchem.2016.03.025

Oxidative addition of halogen across an Os-Os or Os-Sb bond: Formation of five-membered osmium-antimony carbonyl rings

Ying Zhou Li, Rakesh Ganguly, Weng Kee Leong^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Halogenation of the cluster Os₃(CO)₁₀(μ-SbPh₂)₂, 2, with PhICl₂ or I₂ affords the five-membered metallacyclic rings Os₃(Cl)₂(CO)₁₀(μ-SbPh₂)₂, 3d and Os₃(I)₂(CO)₁₀(μ-SbPh₂)₂, 3d-I, respectively, via oxidative addition across an Os-Os bond. The reaction of 2 with SbPh₂Cl or SbPh₂H gives the 3,5-fused rings Os₃(X)(CO)₉(μ-SbPh₂)₃, (X = Cl, 4a; H, 4b), respectively. Halogenation of 4 with PhICl₂ gives the five-membered metallacyclic rings Os₃(Cl)(X)(CO)₉(SbPh₂Cl)(μ-SbPh₂)₂ (X = Cl, 5a; H, 5b) via oxidative addition across an Os-Sb bond. The analogous reaction with I₂ also results in oxidative addition across an Os-Sb bond, but this is followed by displacement of SbPh₂I to afford a five-membered metallacycle containing a μ-I ligand, viz., Os₃(μ-I)(X)(CO)₉(μ-SbPh₂)₂ (X = Cl, 7a, H, 7b).

Original language	English
Pages (from-to)	66-73
Number of pages	8
Journal	Journal of Organometallic Chemistry
Volume	811
DOIs	https://doi.org/10.1016/j.jorganchem.2016.03.025
Publication status	Published - Jun 1 2016
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2016 Elsevier B.V. All rights reserved.

ASJC Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Keywords

Antimony
Five-membered rings
Halogen
Osmium
Oxidative addition

Access to Document

10.1016/j.jorganchem.2016.03.025

Cite this

@article{610f16d38c0a401db219759f8627a81a,

title = "Oxidative addition of halogen across an Os-Os or Os-Sb bond: Formation of five-membered osmium-antimony carbonyl rings",

abstract = "Halogenation of the cluster Os3(CO)10(μ-SbPh2)2, 2, with PhICl2 or I2 affords the five-membered metallacyclic rings Os3(Cl)2(CO)10(μ-SbPh2)2, 3d and Os3(I)2(CO)10(μ-SbPh2)2, 3d-I, respectively, via oxidative addition across an Os-Os bond. The reaction of 2 with SbPh2Cl or SbPh2H gives the 3,5-fused rings Os3(X)(CO)9(μ-SbPh2)3, (X = Cl, 4a; H, 4b), respectively. Halogenation of 4 with PhICl2 gives the five-membered metallacyclic rings Os3(Cl)(X)(CO)9(SbPh2Cl)(μ-SbPh2)2 (X = Cl, 5a; H, 5b) via oxidative addition across an Os-Sb bond. The analogous reaction with I2 also results in oxidative addition across an Os-Sb bond, but this is followed by displacement of SbPh2I to afford a five-membered metallacycle containing a μ-I ligand, viz., Os3(μ-I)(X)(CO)9(μ-SbPh2)2 (X = Cl, 7a, H, 7b).",

keywords = "Antimony, Five-membered rings, Halogen, Osmium, Oxidative addition",

author = "Li, {Ying Zhou} and Rakesh Ganguly and Leong, {Weng Kee}",

year = "2016",

month = jun,

day = "1",

doi = "10.1016/j.jorganchem.2016.03.025",

language = "English",

volume = "811",

pages = "66--73",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

}

TY - JOUR

T1 - Oxidative addition of halogen across an Os-Os or Os-Sb bond

T2 - Formation of five-membered osmium-antimony carbonyl rings

AU - Li, Ying Zhou

AU - Ganguly, Rakesh

AU - Leong, Weng Kee

PY - 2016/6/1

Y1 - 2016/6/1

N2 - Halogenation of the cluster Os3(CO)10(μ-SbPh2)2, 2, with PhICl2 or I2 affords the five-membered metallacyclic rings Os3(Cl)2(CO)10(μ-SbPh2)2, 3d and Os3(I)2(CO)10(μ-SbPh2)2, 3d-I, respectively, via oxidative addition across an Os-Os bond. The reaction of 2 with SbPh2Cl or SbPh2H gives the 3,5-fused rings Os3(X)(CO)9(μ-SbPh2)3, (X = Cl, 4a; H, 4b), respectively. Halogenation of 4 with PhICl2 gives the five-membered metallacyclic rings Os3(Cl)(X)(CO)9(SbPh2Cl)(μ-SbPh2)2 (X = Cl, 5a; H, 5b) via oxidative addition across an Os-Sb bond. The analogous reaction with I2 also results in oxidative addition across an Os-Sb bond, but this is followed by displacement of SbPh2I to afford a five-membered metallacycle containing a μ-I ligand, viz., Os3(μ-I)(X)(CO)9(μ-SbPh2)2 (X = Cl, 7a, H, 7b).

AB - Halogenation of the cluster Os3(CO)10(μ-SbPh2)2, 2, with PhICl2 or I2 affords the five-membered metallacyclic rings Os3(Cl)2(CO)10(μ-SbPh2)2, 3d and Os3(I)2(CO)10(μ-SbPh2)2, 3d-I, respectively, via oxidative addition across an Os-Os bond. The reaction of 2 with SbPh2Cl or SbPh2H gives the 3,5-fused rings Os3(X)(CO)9(μ-SbPh2)3, (X = Cl, 4a; H, 4b), respectively. Halogenation of 4 with PhICl2 gives the five-membered metallacyclic rings Os3(Cl)(X)(CO)9(SbPh2Cl)(μ-SbPh2)2 (X = Cl, 5a; H, 5b) via oxidative addition across an Os-Sb bond. The analogous reaction with I2 also results in oxidative addition across an Os-Sb bond, but this is followed by displacement of SbPh2I to afford a five-membered metallacycle containing a μ-I ligand, viz., Os3(μ-I)(X)(CO)9(μ-SbPh2)2 (X = Cl, 7a, H, 7b).

KW - Antimony

KW - Five-membered rings

KW - Halogen

KW - Osmium

KW - Oxidative addition

UR - http://www.scopus.com/inward/record.url?scp=84961970560&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84961970560&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2016.03.025

DO - 10.1016/j.jorganchem.2016.03.025

M3 - Article

AN - SCOPUS:84961970560

SN - 0022-328X

VL - 811

SP - 66

EP - 73

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Oxidative addition of halogen across an Os-Os or Os-Sb bond: Formation of five-membered osmium-antimony carbonyl rings

Abstract

Bibliographical note

ASJC Scopus Subject Areas

Keywords

Access to Document

Other files and links

Fingerprint

Cite this