Abstract
Palladium catalyzed allylation of menthone and 4-t-butylcyclohexanone derivatives is shown to be under stereoelectronic control leading to the products of axial allylation. The stereochemical assignment is supported by 1H NMR experiments and X-Ray crystallography of selected examples.
| Original language | English |
|---|---|
| Pages (from-to) | 269-276 |
| Number of pages | 8 |
| Journal | Arkivoc |
| Volume | 2001 |
| Issue number | 1 |
| Publication status | Published - 2001 |
| Externally published | Yes |
ASJC Scopus Subject Areas
- Organic Chemistry
Keywords
- Allylation
- Palladium
- Stereoelectronic