Penultimate unit effects in free radical copolymerization

Takeshi Fukuda; Atsushi Goto; Yungwan Kwak; Chiaki Yoshikawa; Yung Dae Ma

doi:10.1002/1521-3900(200206)182:1<53::AID-MASY53>3.0.CO;2-S

Penultimate unit effects in free radical copolymerization

Takeshi Fukuda^*, Atsushi Goto, Yungwan Kwak, Chiaki Yoshikawa, Yung Dae Ma

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

The penultimate unit effects (PUEs) on the propagation, termination, and reversible addition-fragmentation chain transfer (RAFT) processes in free radical copolymerization are discussed on the basis of recent publications. The propriety of the implicit and explicit PUE models in propagation and chain transfer processes is commented. The penultimate termination model with the geometric-mean approximation and the related rate equation are highlighted.

Original language	English
Pages (from-to)	53-64
Number of pages	12
Journal	Macromolecular Symposia
Volume	182
DOIs	https://doi.org/10.1002/1521-3900(200206)182:1<53::AID-MASY53>3.0.CO;2-S
Publication status	Published - 2002
Externally published	Yes

ASJC Scopus Subject Areas

Condensed Matter Physics
Organic Chemistry
Polymers and Plastics
Materials Chemistry

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10.1002/1521-3900(200206)182:1<53::AID-MASY53>3.0.CO;2-S

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abstract = "The penultimate unit effects (PUEs) on the propagation, termination, and reversible addition-fragmentation chain transfer (RAFT) processes in free radical copolymerization are discussed on the basis of recent publications. The propriety of the implicit and explicit PUE models in propagation and chain transfer processes is commented. The penultimate termination model with the geometric-mean approximation and the related rate equation are highlighted.",

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AU - Fukuda, Takeshi

AU - Goto, Atsushi

AU - Kwak, Yungwan

AU - Yoshikawa, Chiaki

AU - Ma, Yung Dae

PY - 2002

Y1 - 2002

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AB - The penultimate unit effects (PUEs) on the propagation, termination, and reversible addition-fragmentation chain transfer (RAFT) processes in free radical copolymerization are discussed on the basis of recent publications. The propriety of the implicit and explicit PUE models in propagation and chain transfer processes is commented. The penultimate termination model with the geometric-mean approximation and the related rate equation are highlighted.

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U2 - 10.1002/1521-3900(200206)182:1<53::AID-MASY53>3.0.CO;2-S

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Penultimate unit effects in free radical copolymerization

Abstract

ASJC Scopus Subject Areas

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