Photochemical reactions of dinuclear organometallic complexes with diphenyl dichalcogenides

Wei Xiang Koh; Jia Li Fong; Ping Xuan Goh; Andrea Paris Gomez; Zhen Xuan Wong; Weng Kee Leong

doi:10.1016/j.jorganchem.2022.122517

Photochemical reactions of dinuclear organometallic complexes with diphenyl dichalcogenides

Wei Xiang Koh, Jia Li Fong, Ping Xuan Goh, Andrea Paris Gomez, Zhen Xuan Wong, Weng Kee Leong^*

^*Corresponding author for this work

Research output: Contribution to journal › Short survey › peer-review

Abstract

The reaction of the dinuclear organometallic complexes [CpRu(CO)₂]₂, [CpMo(CO)₃]₂ and [Cp(OC)₂RuMo(CO)₃Cp] with diphenyl dichalcogenides proceeded under visible light irradiation, via photocleavage of the metal-metal bond. Measurements of the reaction rates point to a preference of the organoruthenium radical for sulfur, and the organomolybdenum radical for selenium.

Original language	English
Article number	122517
Journal	Journal of Organometallic Chemistry
Volume	982
DOIs	https://doi.org/10.1016/j.jorganchem.2022.122517
Publication status	Published - Dec 15 2022
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2022

ASJC Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Keywords

Dichalcogenides
Kinetics
Molybdenum
Radicals
Ruthenium
Se-S bond

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10.1016/j.jorganchem.2022.122517

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title = "Photochemical reactions of dinuclear organometallic complexes with diphenyl dichalcogenides",

abstract = "The reaction of the dinuclear organometallic complexes [CpRu(CO)2]2, [CpMo(CO)3]2 and [Cp(OC)2RuMo(CO)3Cp] with diphenyl dichalcogenides proceeded under visible light irradiation, via photocleavage of the metal-metal bond. Measurements of the reaction rates point to a preference of the organoruthenium radical for sulfur, and the organomolybdenum radical for selenium.",

keywords = "Dichalcogenides, Kinetics, Molybdenum, Radicals, Ruthenium, Se-S bond",

author = "Koh, {Wei Xiang} and Fong, {Jia Li} and Goh, {Ping Xuan} and Gomez, {Andrea Paris} and Wong, {Zhen Xuan} and Leong, {Weng Kee}",

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year = "2022",

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doi = "10.1016/j.jorganchem.2022.122517",

language = "English",

volume = "982",

journal = "Journal of Organometallic Chemistry",

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T1 - Photochemical reactions of dinuclear organometallic complexes with diphenyl dichalcogenides

AU - Koh, Wei Xiang

AU - Fong, Jia Li

AU - Goh, Ping Xuan

AU - Gomez, Andrea Paris

AU - Wong, Zhen Xuan

AU - Leong, Weng Kee

PY - 2022/12/15

Y1 - 2022/12/15

N2 - The reaction of the dinuclear organometallic complexes [CpRu(CO)2]2, [CpMo(CO)3]2 and [Cp(OC)2RuMo(CO)3Cp] with diphenyl dichalcogenides proceeded under visible light irradiation, via photocleavage of the metal-metal bond. Measurements of the reaction rates point to a preference of the organoruthenium radical for sulfur, and the organomolybdenum radical for selenium.

AB - The reaction of the dinuclear organometallic complexes [CpRu(CO)2]2, [CpMo(CO)3]2 and [Cp(OC)2RuMo(CO)3Cp] with diphenyl dichalcogenides proceeded under visible light irradiation, via photocleavage of the metal-metal bond. Measurements of the reaction rates point to a preference of the organoruthenium radical for sulfur, and the organomolybdenum radical for selenium.

KW - Dichalcogenides

KW - Kinetics

KW - Molybdenum

KW - Radicals

KW - Ruthenium

KW - Se-S bond

UR - http://www.scopus.com/inward/record.url?scp=85138326391&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85138326391&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2022.122517

DO - 10.1016/j.jorganchem.2022.122517

M3 - Short survey

AN - SCOPUS:85138326391

SN - 0022-328X

VL - 982

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

M1 - 122517

ER -

Photochemical reactions of dinuclear organometallic complexes with diphenyl dichalcogenides

Abstract

Bibliographical note

ASJC Scopus Subject Areas

Keywords

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