Photoluminescence and growth mechanism of amorphous silica nanowires by vapor phase transport

Y. Yang, B. K. Tay, X. W. Sun*, H. M. Fan, Z. X. Shen

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

18 Citations (Scopus)

Abstract

Amorphous silica [SiOx (1<x<2)] nanowires were fabricated on silicon substrate in an acidic environment by heating the mixture of ZnCl2, and VO2 powders at 1100 °C. The length of SiOx nanowires ranges from micrometers to centimeters, with uniform diameters of 10-500 nm depending on substrate temperature. Room-temperature photoluminescence spectra of the SiOx nanowires showed two strong luminescence peaks in the red and green region, respectively. The photoluminescence was suggested to originate from nonbridging oxygen hole center (red band), and hydrogen-related species in the structure of SiOx (green band). The study on chemical reactions and growth of the SiOx nanowires revealed the formation process of silica nanowires in acidic environment was closely related to the vapor-solid-liquid mechanism.

Original languageEnglish
Pages (from-to)218-223
Number of pages6
JournalPhysica E: Low-Dimensional Systems and Nanostructures
Volume31
Issue number2
DOIs
Publication statusPublished - Mar 2006
Externally publishedYes

ASJC Scopus Subject Areas

  • Electronic, Optical and Magnetic Materials
  • Atomic and Molecular Physics, and Optics
  • Condensed Matter Physics

Keywords

  • Photoluminescence
  • Silica nanowires
  • Vapor phase transport

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