Photolysis of an alkoxyamine using intramolecular energy transfer from a quinoline antenna - Towards photo-induced living radical polymerization

Atsushi Goto*, J. C. Scaiano, Luca Maretti

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

70 Citations (Scopus)

Abstract

The photolysis of an alkoxyamine triad comprised of the 1-phenylethyl moiety, 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) and 2-methyl-3-hydroxy quinoline leads to energy transfer from the quinoline moiety (antenna) and cleavage of the C-O alkoxyamine bond, suggesting its possible applications in low temperature living free radical polymerization.

Original languageEnglish
Pages (from-to)833-835
Number of pages3
JournalPhotochemical and Photobiological Sciences
Volume6
Issue number8
DOIs
Publication statusPublished - 2007
Externally publishedYes

ASJC Scopus Subject Areas

  • Physical and Theoretical Chemistry

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