Polyaniline nanoparticles doped with star-like poly(styrene sulfonate): Synthesis and electrochromic properties

Jia Wei; Shanxin Xiong; Yu Bai; Pengtao Jia; Jan Ma; Xuehong Lu

doi:10.1016/j.solmat.2011.05.016

Polyaniline nanoparticles doped with star-like poly(styrene sulfonate): Synthesis and electrochromic properties

Jia Wei, Shanxin Xiong, Yu Bai, Pengtao Jia, Jan Ma, Xuehong Lu^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

Poly(styrene sulfonate) (PSS) tethered polyhedral oligomeric silsesquioxane (POSS-PSS) was synthesized and used as star-like dopant for the preparation of coreshell polyaniline/POSS-PSS (PANI/POSS-PSS) nanoparticles. The prepared aqueous emulsion shows good processibility and high stability. The electrochemical characteristics and electrochromic properties of PANI/POSS-PSS were studied. In comparison with polyaniline (PANI) doped with linear PSS dopant, the star-like POSS-PSS dopant renders PANI/POSS-PSS-based electrochromic device higher optical contrast and faster switching speed owing to the faster ion transportation resulting from the porous morphology of PANI/POSS-PSS.

Original language	English
Pages (from-to)	141-147
Number of pages	7
Journal	Solar Energy Materials and Solar Cells
Volume	99
DOIs	https://doi.org/10.1016/j.solmat.2011.05.016
Publication status	Published - Apr 2012
Externally published	Yes

ASJC Scopus Subject Areas

Electronic, Optical and Magnetic Materials
Renewable Energy, Sustainability and the Environment
Surfaces, Coatings and Films

Keywords

Dopant
Electrochromism
Optical contrast
Polyaniline
Polyhedral oligomeric silsesquioxane

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.solmat.2011.05.016

Cite this

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title = "Polyaniline nanoparticles doped with star-like poly(styrene sulfonate): Synthesis and electrochromic properties",

abstract = "Poly(styrene sulfonate) (PSS) tethered polyhedral oligomeric silsesquioxane (POSS-PSS) was synthesized and used as star-like dopant for the preparation of coreshell polyaniline/POSS-PSS (PANI/POSS-PSS) nanoparticles. The prepared aqueous emulsion shows good processibility and high stability. The electrochemical characteristics and electrochromic properties of PANI/POSS-PSS were studied. In comparison with polyaniline (PANI) doped with linear PSS dopant, the star-like POSS-PSS dopant renders PANI/POSS-PSS-based electrochromic device higher optical contrast and faster switching speed owing to the faster ion transportation resulting from the porous morphology of PANI/POSS-PSS.",

keywords = "Dopant, Electrochromism, Optical contrast, Polyaniline, Polyhedral oligomeric silsesquioxane",

author = "Jia Wei and Shanxin Xiong and Yu Bai and Pengtao Jia and Jan Ma and Xuehong Lu",

year = "2012",

month = apr,

doi = "10.1016/j.solmat.2011.05.016",

language = "English",

volume = "99",

pages = "141--147",

journal = "Solar Energy Materials and Solar Cells",

issn = "0927-0248",

publisher = "Elsevier",

}

TY - JOUR

T1 - Polyaniline nanoparticles doped with star-like poly(styrene sulfonate)

T2 - Synthesis and electrochromic properties

AU - Wei, Jia

AU - Xiong, Shanxin

AU - Bai, Yu

AU - Jia, Pengtao

AU - Ma, Jan

AU - Lu, Xuehong

PY - 2012/4

Y1 - 2012/4

N2 - Poly(styrene sulfonate) (PSS) tethered polyhedral oligomeric silsesquioxane (POSS-PSS) was synthesized and used as star-like dopant for the preparation of coreshell polyaniline/POSS-PSS (PANI/POSS-PSS) nanoparticles. The prepared aqueous emulsion shows good processibility and high stability. The electrochemical characteristics and electrochromic properties of PANI/POSS-PSS were studied. In comparison with polyaniline (PANI) doped with linear PSS dopant, the star-like POSS-PSS dopant renders PANI/POSS-PSS-based electrochromic device higher optical contrast and faster switching speed owing to the faster ion transportation resulting from the porous morphology of PANI/POSS-PSS.

AB - Poly(styrene sulfonate) (PSS) tethered polyhedral oligomeric silsesquioxane (POSS-PSS) was synthesized and used as star-like dopant for the preparation of coreshell polyaniline/POSS-PSS (PANI/POSS-PSS) nanoparticles. The prepared aqueous emulsion shows good processibility and high stability. The electrochemical characteristics and electrochromic properties of PANI/POSS-PSS were studied. In comparison with polyaniline (PANI) doped with linear PSS dopant, the star-like POSS-PSS dopant renders PANI/POSS-PSS-based electrochromic device higher optical contrast and faster switching speed owing to the faster ion transportation resulting from the porous morphology of PANI/POSS-PSS.

KW - Dopant

KW - Electrochromism

KW - Optical contrast

KW - Polyaniline

KW - Polyhedral oligomeric silsesquioxane

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DO - 10.1016/j.solmat.2011.05.016

M3 - Article

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SN - 0927-0248

VL - 99

SP - 141

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JO - Solar Energy Materials and Solar Cells

JF - Solar Energy Materials and Solar Cells

ER -

Polyaniline nanoparticles doped with star-like poly(styrene sulfonate): Synthesis and electrochromic properties

Abstract

ASJC Scopus Subject Areas

Keywords

UN SDGs

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