Preparation and X-ray structure of a novel delocalized diphosphazene complex: [Os3(CO)11{(CF3)2PNPPh3}]

H. G. Ang; Y. M. Cai; W. L. Kwik; W. K. Leong; D. A. Tocher

doi:10.1016/S0277-5387(00)86124-0

Preparation and X-ray structure of a novel delocalized diphosphazene complex: [Os₃(CO)₁₁{(CF₃)₂PNPPh₃}]

H. G. Ang^*, Y. M. Cai, W. L. Kwik, W. K. Leong, D. A. Tocher

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The title compound 1, obtained from the reaction of [Os₃(CO)₁₁(CH₃CN)] with (CF₃)₂PNPPh₃, has been characterized by spectroscopic and X-ray structural analyses. The osmium atoms form an approximate isosceles triangle with an equatorial site being taken up by the diphosphazene ligand. The PNP moiety is nearly linear and the two PN bonds are equivalent.

Original language	English
Pages (from-to)	881-882
Number of pages	2
Journal	Polyhedron
Volume	10
Issue number	8
DOIs	https://doi.org/10.1016/S0277-5387(00)86124-0
Publication status	Published - 1991
Externally published	Yes

ASJC Scopus Subject Areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "Preparation and X-ray structure of a novel delocalized diphosphazene complex: [Os3(CO)11{(CF3)2PNPPh3}]",

abstract = "The title compound 1, obtained from the reaction of [Os3(CO)11(CH3CN)] with (CF3)2PNPPh3, has been characterized by spectroscopic and X-ray structural analyses. The osmium atoms form an approximate isosceles triangle with an equatorial site being taken up by the diphosphazene ligand. The PNP moiety is nearly linear and the two PN bonds are equivalent.",

author = "Ang, {H. G.} and Cai, {Y. M.} and Kwik, {W. L.} and Leong, {W. K.} and Tocher, {D. A.}",

year = "1991",

doi = "10.1016/S0277-5387(00)86124-0",

language = "English",

volume = "10",

pages = "881--882",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Limited",

number = "8",

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TY - JOUR

T1 - Preparation and X-ray structure of a novel delocalized diphosphazene complex

T2 - [Os3(CO)11{(CF3)2PNPPh3}]

AU - Ang, H. G.

AU - Cai, Y. M.

AU - Kwik, W. L.

AU - Leong, W. K.

AU - Tocher, D. A.

PY - 1991

Y1 - 1991

N2 - The title compound 1, obtained from the reaction of [Os3(CO)11(CH3CN)] with (CF3)2PNPPh3, has been characterized by spectroscopic and X-ray structural analyses. The osmium atoms form an approximate isosceles triangle with an equatorial site being taken up by the diphosphazene ligand. The PNP moiety is nearly linear and the two PN bonds are equivalent.

AB - The title compound 1, obtained from the reaction of [Os3(CO)11(CH3CN)] with (CF3)2PNPPh3, has been characterized by spectroscopic and X-ray structural analyses. The osmium atoms form an approximate isosceles triangle with an equatorial site being taken up by the diphosphazene ligand. The PNP moiety is nearly linear and the two PN bonds are equivalent.

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U2 - 10.1016/S0277-5387(00)86124-0

DO - 10.1016/S0277-5387(00)86124-0

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SN - 0277-5387

VL - 10

SP - 881

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JO - Polyhedron

JF - Polyhedron

IS - 8

ER -

Preparation and X-ray structure of a novel delocalized diphosphazene complex: [Os₃(CO)₁₁{(CF₃)₂PNPPh₃}]

Abstract

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