Pyridine-Fused Azacorannulene: Fine-Tuning of the Structure and Properties of Nitrogen-Embedded Buckybowls

Kimihiro Nakamura; Kotaro Ochiai; Ayaka Yubuta; Dan He; Daigo Miyajima; Shingo Ito

doi:10.1021/prechem.3c00004

Pyridine-Fused Azacorannulene: Fine-Tuning of the Structure and Properties of Nitrogen-Embedded Buckybowls

Kimihiro Nakamura, Kotaro Ochiai, Ayaka Yubuta, Dan He, Daigo Miyajima, Shingo Ito^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Heteroatom-embedded buckybowl molecules provide a fundamental molecular framework that has potential applications in various research fields. However, selective introduction of heteroatoms into buckybowls is challenging, and thus, studies investigating the effect of introduced heteroatoms have been limited. Here, we report the synthesis of pyridine-fused azacorannulene molecules. The influence of nitrogen atoms introduced into the peripheral positions on the structural, electronic, and optical properties is discussed.

Original language	English
Pages (from-to)	29-33
Number of pages	5
Journal	Precision Chemistry
Volume	1
Issue number	1
DOIs	https://doi.org/10.1021/prechem.3c00004
Publication status	Published - Mar 27 2023
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2023 The Authors. Co-published by University of Science and Technology of China and American Chemical Society.

ASJC Scopus Subject Areas

General

Keywords

1,3-Dipolar Cycloaddition
Azacorannulene
Azomethine Ylide
Buckybowl
Polycyclic Aromatic Molecule

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10.1021/prechem.3c00004

Cite this

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note = "Publisher Copyright: {\textcopyright} 2023 The Authors. Co-published by University of Science and Technology of China and American Chemical Society.",

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doi = "10.1021/prechem.3c00004",

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T1 - Pyridine-Fused Azacorannulene

T2 - Fine-Tuning of the Structure and Properties of Nitrogen-Embedded Buckybowls

AU - Nakamura, Kimihiro

AU - Ochiai, Kotaro

AU - Yubuta, Ayaka

AU - He, Dan

AU - Miyajima, Daigo

AU - Ito, Shingo

PY - 2023/3/27

Y1 - 2023/3/27

N2 - Heteroatom-embedded buckybowl molecules provide a fundamental molecular framework that has potential applications in various research fields. However, selective introduction of heteroatoms into buckybowls is challenging, and thus, studies investigating the effect of introduced heteroatoms have been limited. Here, we report the synthesis of pyridine-fused azacorannulene molecules. The influence of nitrogen atoms introduced into the peripheral positions on the structural, electronic, and optical properties is discussed.

AB - Heteroatom-embedded buckybowl molecules provide a fundamental molecular framework that has potential applications in various research fields. However, selective introduction of heteroatoms into buckybowls is challenging, and thus, studies investigating the effect of introduced heteroatoms have been limited. Here, we report the synthesis of pyridine-fused azacorannulene molecules. The influence of nitrogen atoms introduced into the peripheral positions on the structural, electronic, and optical properties is discussed.

KW - 1,3-Dipolar Cycloaddition

KW - Azacorannulene

KW - Azomethine Ylide

KW - Buckybowl

KW - Polycyclic Aromatic Molecule

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Pyridine-Fused Azacorannulene: Fine-Tuning of the Structure and Properties of Nitrogen-Embedded Buckybowls

Abstract

Bibliographical note

ASJC Scopus Subject Areas

Keywords

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Research from Nanyang Technological University in the Area of Nitrogen Published (Pyridine-Fused Azacorannulene: Fine-Tuning of the Structure and Properties of Nitrogen-Embedded Buckybowls)

Cite this

Pyridine-Fused Azacorannulene: Fine-Tuning of the Structure and Properties of Nitrogen-Embedded Buckybowls

Abstract

Bibliographical note

ASJC Scopus Subject Areas

Keywords

Access to Document

Other files and links

Fingerprint

Press/Media

Research from Nanyang Technological University in the Area of Nitrogen Published (Pyridine-Fused Azacorannulene: Fine-Tuning of the Structure and Properties of Nitrogen-Embedded Buckybowls)

Cite this