Reaction of Cp*Ir(CO)2 with activated perfluoroaromatic compounds: Formation of metallocarboxylic acids via aromatic nucleophilic substitution

Pek Ke Chan; Weng Kee Leong

doi:10.1021/om701078q

Reaction of Cp*Ir(CO)₂ with activated perfluoroaromatic compounds: Formation of metallocarboxylic acids via aromatic nucleophilic substitution

Pek Ke Chan, Weng Kee Leong

National University of Singapore

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

The reaction of Cp*Ir(CO)₂ with activated perfluoroaromatic compounds such as pentafluoropyridine and -benzonitrile afforded the metallocarboxylic acids Cp*Ir(COOH)(L)(CO), L = C ₅F₄N or C₆F₄CN, respectively. The reaction probably proceeds via aromatic nucleophilic substitution followed by nucleophilic attack by water at one of the carbonyl ligands.

Original language	English
Pages (from-to)	1247-1253
Number of pages	7
Journal	Organometallics
Volume	27
Issue number	6
DOIs	https://doi.org/10.1021/om701078q
Publication status	Published - Mar 24 2008
Externally published	Yes

ASJC Scopus Subject Areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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abstract = "The reaction of Cp*Ir(CO)2 with activated perfluoroaromatic compounds such as pentafluoropyridine and -benzonitrile afforded the metallocarboxylic acids Cp*Ir(COOH)(L)(CO), L = C 5F4N or C6F4CN, respectively. The reaction probably proceeds via aromatic nucleophilic substitution followed by nucleophilic attack by water at one of the carbonyl ligands.",

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AU - Leong, Weng Kee

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AB - The reaction of Cp*Ir(CO)2 with activated perfluoroaromatic compounds such as pentafluoropyridine and -benzonitrile afforded the metallocarboxylic acids Cp*Ir(COOH)(L)(CO), L = C 5F4N or C6F4CN, respectively. The reaction probably proceeds via aromatic nucleophilic substitution followed by nucleophilic attack by water at one of the carbonyl ligands.

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Reaction of Cp*Ir(CO)₂ with activated perfluoroaromatic compounds: Formation of metallocarboxylic acids via aromatic nucleophilic substitution

Abstract

ASJC Scopus Subject Areas

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