Reaction of the heteronuclear cluster RuOs3(μ-H) 2(CO)13 with diphenylacetylene: An alkyne bound to a tetrahedral metal core

Yong Leng Kelvin Tan; Chin Wai Alaric Koh; Ting Bin Lim; Weng Kee Leong

doi:10.1007/s10876-006-0072-y

Reaction of the heteronuclear cluster RuOs₃(μ-H) ₂(CO)₁₃ with diphenylacetylene: An alkyne bound to a tetrahedral metal core

Yong Leng Kelvin Tan, Chin Wai Alaric Koh, Ting Bin Lim, Weng Kee Leong^*

^*Corresponding author for this work

National University of Singapore

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Reaction of the heteronuclear cluster RuOs₃(μ-H) ₂(CO)₁₃, 1, with diphenylacetylene afforded the tetrahedral cluster RuOs₃(μ-H)₂(μ₃, η¹:η²:η¹-C₂Ph ₂)(CO)₁₁, 2, in good yield. Spectroscopic evidence suggests that 2 exist as two isomers in solution.

Original language	English
Pages (from-to)	509-516
Number of pages	8
Journal	Journal of Cluster Science
Volume	17
Issue number	3
DOIs	https://doi.org/10.1007/s10876-006-0072-y
Publication status	Published - Sept 2006
Externally published	Yes

ASJC Scopus Subject Areas

General Chemistry
Biochemistry
General Materials Science
Condensed Matter Physics

Keywords

Alkyne
Cluster
Heteronuclear
Isomers
Osmium
Ruthenium

Access to Document

10.1007/s10876-006-0072-y

Cite this

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title = "Reaction of the heteronuclear cluster RuOs3(μ-H) 2(CO)13 with diphenylacetylene: An alkyne bound to a tetrahedral metal core",

abstract = "Reaction of the heteronuclear cluster RuOs3(μ-H) 2(CO)13, 1, with diphenylacetylene afforded the tetrahedral cluster RuOs3(μ-H)2(μ3, η1:η2:η1-C2Ph 2)(CO)11, 2, in good yield. Spectroscopic evidence suggests that 2 exist as two isomers in solution.",

keywords = "Alkyne, Cluster, Heteronuclear, Isomers, Osmium, Ruthenium",

author = "Tan, {Yong Leng Kelvin} and Koh, {Chin Wai Alaric} and Lim, {Ting Bin} and Leong, {Weng Kee}",

year = "2006",

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doi = "10.1007/s10876-006-0072-y",

language = "English",

volume = "17",

pages = "509--516",

journal = "Journal of Cluster Science",

issn = "1040-7278",

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T1 - Reaction of the heteronuclear cluster RuOs3(μ-H) 2(CO)13 with diphenylacetylene

T2 - An alkyne bound to a tetrahedral metal core

AU - Tan, Yong Leng Kelvin

AU - Koh, Chin Wai Alaric

AU - Lim, Ting Bin

AU - Leong, Weng Kee

PY - 2006/9

Y1 - 2006/9

N2 - Reaction of the heteronuclear cluster RuOs3(μ-H) 2(CO)13, 1, with diphenylacetylene afforded the tetrahedral cluster RuOs3(μ-H)2(μ3, η1:η2:η1-C2Ph 2)(CO)11, 2, in good yield. Spectroscopic evidence suggests that 2 exist as two isomers in solution.

AB - Reaction of the heteronuclear cluster RuOs3(μ-H) 2(CO)13, 1, with diphenylacetylene afforded the tetrahedral cluster RuOs3(μ-H)2(μ3, η1:η2:η1-C2Ph 2)(CO)11, 2, in good yield. Spectroscopic evidence suggests that 2 exist as two isomers in solution.

KW - Alkyne

KW - Cluster

KW - Heteronuclear

KW - Isomers

KW - Osmium

KW - Ruthenium

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U2 - 10.1007/s10876-006-0072-y

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JO - Journal of Cluster Science

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