Reaction of the heteronuclear cluster RuOs3(μ-H) 2(CO)13 with toluene

Yong Leng Kelvin Tan; Weng Kee Leong

doi:10.1016/j.jorganchem.2006.01.008

Reaction of the heteronuclear cluster RuOs₃(μ-H) ₂(CO)₁₃ with toluene

Yong Leng Kelvin Tan, Weng Kee Leong^*

^*Corresponding author for this work

National University of Singapore

Research output: Contribution to journal › Short survey › peer-review

8 Citations (Scopus)

Abstract

The heteronuclear cluster RuOs₃(μ-H)₂(CO) ₁₃ (4) reacts with refluxing toluene to form the clusters Ru ₂Os₃(μ-H)₂(CO)₁₆ (5) RuOs ₃(CO)₉(μ-CO)₂(η⁶-C ₆H₅Me) (6) and Ru₂Os₃(CO) ₁₂(μ-CO)(η⁶-C₆H₅Me) (7). Cluster 5 exists as a mixture of five isomers. The inter-relationship among the clusters has also been investigated.

Original language	English
Pages (from-to)	2048-2054
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	691
Issue number	9
DOIs	https://doi.org/10.1016/j.jorganchem.2006.01.008
Publication status	Published - Apr 15 2006
Externally published	Yes

ASJC Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Keywords

Heterometallic complexes
Isomers
Osmium
Ruthenium
Toluene

Access to Document

10.1016/j.jorganchem.2006.01.008

Cite this

@article{d02ce5c229544432941af13afe138f0f,

title = "Reaction of the heteronuclear cluster RuOs3(μ-H) 2(CO)13 with toluene",

abstract = "The heteronuclear cluster RuOs3(μ-H)2(CO) 13 (4) reacts with refluxing toluene to form the clusters Ru 2Os3(μ-H)2(CO)16 (5) RuOs 3(CO)9(μ-CO)2(η6-C 6H5Me) (6) and Ru2Os3(CO) 12(μ-CO)(η6-C6H5Me) (7). Cluster 5 exists as a mixture of five isomers. The inter-relationship among the clusters has also been investigated.",

keywords = "Heterometallic complexes, Isomers, Osmium, Ruthenium, Toluene",

author = "Tan, {Yong Leng Kelvin} and Leong, {Weng Kee}",

year = "2006",

month = apr,

day = "15",

doi = "10.1016/j.jorganchem.2006.01.008",

language = "English",

volume = "691",

pages = "2048--2054",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "9",

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TY - JOUR

T1 - Reaction of the heteronuclear cluster RuOs3(μ-H) 2(CO)13 with toluene

AU - Tan, Yong Leng Kelvin

AU - Leong, Weng Kee

PY - 2006/4/15

Y1 - 2006/4/15

N2 - The heteronuclear cluster RuOs3(μ-H)2(CO) 13 (4) reacts with refluxing toluene to form the clusters Ru 2Os3(μ-H)2(CO)16 (5) RuOs 3(CO)9(μ-CO)2(η6-C 6H5Me) (6) and Ru2Os3(CO) 12(μ-CO)(η6-C6H5Me) (7). Cluster 5 exists as a mixture of five isomers. The inter-relationship among the clusters has also been investigated.

AB - The heteronuclear cluster RuOs3(μ-H)2(CO) 13 (4) reacts with refluxing toluene to form the clusters Ru 2Os3(μ-H)2(CO)16 (5) RuOs 3(CO)9(μ-CO)2(η6-C 6H5Me) (6) and Ru2Os3(CO) 12(μ-CO)(η6-C6H5Me) (7). Cluster 5 exists as a mixture of five isomers. The inter-relationship among the clusters has also been investigated.

KW - Heterometallic complexes

KW - Isomers

KW - Osmium

KW - Ruthenium

KW - Toluene

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U2 - 10.1016/j.jorganchem.2006.01.008

DO - 10.1016/j.jorganchem.2006.01.008

M3 - Short survey

AN - SCOPUS:33645388413

SN - 0022-328X

VL - 691

SP - 2048

EP - 2054

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 9

ER -