Reactions of the triosmium cluster Os3(μ-H) (μ-OH)(CO)10 with naphthols

Mien Wei Lum; Weng Kee Leong

doi:10.1016/j.jorganchem.2003.08.030

Reactions of the triosmium cluster Os₃(μ-H) (μ-OH)(CO)₁₀ with naphthols

Mien Wei Lum, Weng Kee Leong^*

^*Corresponding author for this work

National University of Singapore

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Reaction of the cluster Os₃(μ-H) (μ-OH)(CO)₁₀ (1) with 1-naphthol afforded the isomeric clusters 2a and 3a with the formulae Os₃(μ-H)₂ (μ₃-1-OC₁₀H₆)(CO)₉. A similar reaction with 2-naphthol, however, gave Os₃(μ-H) (μ-2-OC₁₀H₇)(CO)₁₀, 4b, and the analogue of 2a. These clusters have been structurally characterised to confirm the mode of anchoring of the naphthols.

Original language	English
Pages (from-to)	203-208
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	687
Issue number	1
DOIs	https://doi.org/10.1016/j.jorganchem.2003.08.030
Publication status	Published - Dec 1 2003
Externally published	Yes

ASJC Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Keywords

Clusters
Naphthol
Osmium

Access to Document

10.1016/j.jorganchem.2003.08.030

Cite this

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title = "Reactions of the triosmium cluster Os3(μ-H) (μ-OH)(CO)10 with naphthols",

abstract = "Reaction of the cluster Os3(μ-H) (μ-OH)(CO)10 (1) with 1-naphthol afforded the isomeric clusters 2a and 3a with the formulae Os3(μ-H)2 (μ3-1-OC10H6)(CO)9. A similar reaction with 2-naphthol, however, gave Os3(μ-H) (μ-2-OC10H7)(CO)10, 4b, and the analogue of 2a. These clusters have been structurally characterised to confirm the mode of anchoring of the naphthols.",

keywords = "Clusters, Naphthol, Osmium",

author = "Lum, {Mien Wei} and Leong, {Weng Kee}",

year = "2003",

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journal = "Journal of Organometallic Chemistry",

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T1 - Reactions of the triosmium cluster Os3(μ-H) (μ-OH)(CO)10 with naphthols

AU - Lum, Mien Wei

AU - Leong, Weng Kee

PY - 2003/12/1

Y1 - 2003/12/1

N2 - Reaction of the cluster Os3(μ-H) (μ-OH)(CO)10 (1) with 1-naphthol afforded the isomeric clusters 2a and 3a with the formulae Os3(μ-H)2 (μ3-1-OC10H6)(CO)9. A similar reaction with 2-naphthol, however, gave Os3(μ-H) (μ-2-OC10H7)(CO)10, 4b, and the analogue of 2a. These clusters have been structurally characterised to confirm the mode of anchoring of the naphthols.

AB - Reaction of the cluster Os3(μ-H) (μ-OH)(CO)10 (1) with 1-naphthol afforded the isomeric clusters 2a and 3a with the formulae Os3(μ-H)2 (μ3-1-OC10H6)(CO)9. A similar reaction with 2-naphthol, however, gave Os3(μ-H) (μ-2-OC10H7)(CO)10, 4b, and the analogue of 2a. These clusters have been structurally characterised to confirm the mode of anchoring of the naphthols.

KW - Clusters

KW - Naphthol

KW - Osmium

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DO - 10.1016/j.jorganchem.2003.08.030

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