Reactivity of Cyclic (Alkyl)(amino)germylene towards Copper(I) and Gold(I) Complexes

Zhongtao Feng; Liliang Wang; Sharifah Nadhirah Binte Shaik Mohammed; Bin Rao; Rei Kinjo

doi:10.1002/asia.202300634

Reactivity of Cyclic (Alkyl)(amino)germylene towards Copper(I) and Gold(I) Complexes

Zhongtao Feng, Liliang Wang, Sharifah Nadhirah Binte Shaik Mohammed, Bin Rao, Rei Kinjo^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The reactions of cyclic (alkyl)(amino)germylenes (CAAGe) with copper(I) and gold(I) complexes were investigated. CAAGe (1) reacts with CuBr(SMe₂) leading to a tetrameric germylene complex [CAAGeCuBr]₄ (2), whereas CAAGe (3) undergoes Au−Cl bond insertion with LAuCl (L=phosphine or N-heterocyclic carbene) to afford germanium gold(I) complexes (5 and 6). Chlorine abstraction of 6 gives the cationic germylene gold(I) complex 7.

Original language	English
Article number	e202300634
Journal	Chemistry - An Asian Journal
Volume	18
Issue number	19
DOIs	https://doi.org/10.1002/asia.202300634
Publication status	Published - Oct 4 2023
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2023 Wiley-VCH GmbH.

ASJC Scopus Subject Areas

Biochemistry
General Chemistry
Organic Chemistry

Keywords

coordination
copper
crystal structure
germylene
gold

Access to Document

10.1002/asia.202300634

Cite this

@article{be183694ef904a769fdf996164ebaaf4,

title = "Reactivity of Cyclic (Alkyl)(amino)germylene towards Copper(I) and Gold(I) Complexes",

abstract = "The reactions of cyclic (alkyl)(amino)germylenes (CAAGe) with copper(I) and gold(I) complexes were investigated. CAAGe (1) reacts with CuBr(SMe2) leading to a tetrameric germylene complex [CAAGeCuBr]4 (2), whereas CAAGe (3) undergoes Au−Cl bond insertion with LAuCl (L=phosphine or N-heterocyclic carbene) to afford germanium gold(I) complexes (5 and 6). Chlorine abstraction of 6 gives the cationic germylene gold(I) complex 7.",

keywords = "coordination, copper, crystal structure, germylene, gold",

author = "Zhongtao Feng and Liliang Wang and Mohammed, {Sharifah Nadhirah Binte Shaik} and Bin Rao and Rei Kinjo",

note = "Publisher Copyright: {\textcopyright} 2023 Wiley-VCH GmbH.",

year = "2023",

month = oct,

day = "4",

doi = "10.1002/asia.202300634",

language = "English",

volume = "18",

journal = "Chemistry - An Asian Journal",

issn = "1861-4728",

publisher = "John Wiley and Sons Ltd",

number = "19",

}

TY - JOUR

T1 - Reactivity of Cyclic (Alkyl)(amino)germylene towards Copper(I) and Gold(I) Complexes

AU - Feng, Zhongtao

AU - Wang, Liliang

AU - Mohammed, Sharifah Nadhirah Binte Shaik

AU - Rao, Bin

AU - Kinjo, Rei

PY - 2023/10/4

Y1 - 2023/10/4

N2 - The reactions of cyclic (alkyl)(amino)germylenes (CAAGe) with copper(I) and gold(I) complexes were investigated. CAAGe (1) reacts with CuBr(SMe2) leading to a tetrameric germylene complex [CAAGeCuBr]4 (2), whereas CAAGe (3) undergoes Au−Cl bond insertion with LAuCl (L=phosphine or N-heterocyclic carbene) to afford germanium gold(I) complexes (5 and 6). Chlorine abstraction of 6 gives the cationic germylene gold(I) complex 7.

AB - The reactions of cyclic (alkyl)(amino)germylenes (CAAGe) with copper(I) and gold(I) complexes were investigated. CAAGe (1) reacts with CuBr(SMe2) leading to a tetrameric germylene complex [CAAGeCuBr]4 (2), whereas CAAGe (3) undergoes Au−Cl bond insertion with LAuCl (L=phosphine or N-heterocyclic carbene) to afford germanium gold(I) complexes (5 and 6). Chlorine abstraction of 6 gives the cationic germylene gold(I) complex 7.

KW - coordination

KW - copper

KW - crystal structure

KW - germylene

KW - gold

UR - http://www.scopus.com/inward/record.url?scp=85170089527&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85170089527&partnerID=8YFLogxK

U2 - 10.1002/asia.202300634

DO - 10.1002/asia.202300634

M3 - Article

AN - SCOPUS:85170089527

SN - 1861-4728

VL - 18

JO - Chemistry - An Asian Journal

JF - Chemistry - An Asian Journal

IS - 19

M1 - e202300634

ER -

Reactivity of Cyclic (Alkyl)(amino)germylene towards Copper(I) and Gold(I) Complexes

Abstract

Bibliographical note

ASJC Scopus Subject Areas

Keywords

Access to Document

Other files and links

Fingerprint

Cite this