Reactivity of the heteronuclear cluster RuOs3(μ-H)2(CO)13 with indene

Yong Leng Kelvin Tan; Weng Kee Leong

doi:10.1016/j.jorganchem.2006.10.010

Reactivity of the heteronuclear cluster RuOs₃(μ-H)₂(CO)₁₃ with indene

Yong Leng Kelvin Tan, Weng Kee Leong^*

^*Corresponding author for this work

National University of Singapore

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

The heteronuclear cluster RuOs₃(μ-H)₂(CO)₁₃ (1) reacts with indene under thermal activation to afford the novel clusters RuOs₃(μ-H)(CO)₉(μ-CO)₂(η ⁵-C₉H₇) (3), RuOs₃(μ-H)(CO)₉(μ₃,η ⁵:η²:η²-C₉H₇) (4) and Ru₂Os₃(μ-H)(CO)₁₁(μ₃, η⁵:η²:η²-C₉H₇) (5), the latter two possessing indenyl ligands in the μ₃,η⁵:η²:η² bonding mode. Cluster 5 exists as a mixture of two isomers. The inter-relationship among the clusters has also been investigated.

Original language	English
Pages (from-to)	768-773
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	692
Issue number	4
DOIs	https://doi.org/10.1016/j.jorganchem.2006.10.010
Publication status	Published - Jan 15 2007
Externally published	Yes

ASJC Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Keywords

Heterometallic clusters
Indene
Isomers
Osmium
Ruthenium

Access to Document

10.1016/j.jorganchem.2006.10.010

Cite this

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title = "Reactivity of the heteronuclear cluster RuOs3(μ-H)2(CO)13 with indene",

abstract = "The heteronuclear cluster RuOs3(μ-H)2(CO)13 (1) reacts with indene under thermal activation to afford the novel clusters RuOs3(μ-H)(CO)9(μ-CO)2(η 5-C9H7) (3), RuOs3(μ-H)(CO)9(μ3,η 5:η2:η2-C9H7) (4) and Ru2Os3(μ-H)(CO)11(μ3, η5:η2:η2-C9H 7) (5), the latter two possessing indenyl ligands in the μ3,η5:η2:η2 bonding mode. Cluster 5 exists as a mixture of two isomers. The inter-relationship among the clusters has also been investigated.",

keywords = "Heterometallic clusters, Indene, Isomers, Osmium, Ruthenium",

author = "Tan, {Yong Leng Kelvin} and Leong, {Weng Kee}",

year = "2007",

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doi = "10.1016/j.jorganchem.2006.10.010",

language = "English",

volume = "692",

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journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

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T1 - Reactivity of the heteronuclear cluster RuOs3(μ-H)2(CO)13 with indene

AU - Tan, Yong Leng Kelvin

AU - Leong, Weng Kee

PY - 2007/1/15

Y1 - 2007/1/15

N2 - The heteronuclear cluster RuOs3(μ-H)2(CO)13 (1) reacts with indene under thermal activation to afford the novel clusters RuOs3(μ-H)(CO)9(μ-CO)2(η 5-C9H7) (3), RuOs3(μ-H)(CO)9(μ3,η 5:η2:η2-C9H7) (4) and Ru2Os3(μ-H)(CO)11(μ3, η5:η2:η2-C9H 7) (5), the latter two possessing indenyl ligands in the μ3,η5:η2:η2 bonding mode. Cluster 5 exists as a mixture of two isomers. The inter-relationship among the clusters has also been investigated.

AB - The heteronuclear cluster RuOs3(μ-H)2(CO)13 (1) reacts with indene under thermal activation to afford the novel clusters RuOs3(μ-H)(CO)9(μ-CO)2(η 5-C9H7) (3), RuOs3(μ-H)(CO)9(μ3,η 5:η2:η2-C9H7) (4) and Ru2Os3(μ-H)(CO)11(μ3, η5:η2:η2-C9H 7) (5), the latter two possessing indenyl ligands in the μ3,η5:η2:η2 bonding mode. Cluster 5 exists as a mixture of two isomers. The inter-relationship among the clusters has also been investigated.

KW - Heterometallic clusters

KW - Indene

KW - Isomers

KW - Osmium

KW - Ruthenium

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