Reduced overlap population analysis for triosmium clusters

Elizabeth C. Morrison; Weng Kee Leong; Jialin Tan

doi:10.1007/s10876-007-0138-5

Reduced overlap population analysis for triosmium clusters

Elizabeth C. Morrison, Weng Kee Leong^*, Jialin Tan

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The use of reduced overlap population (ROP) analysis from EHMO calculations as a means to gauge the presence of metal-metal bonds in triosmium clusters is examined. A number of triosmium clusters containing bridging ligands have been used as test cases, including the bis-ethoxy bridged cluster Os ₃(μ-OEt)₂(CO)₁₀, 1b, and some of its group 15 derivatives Os₃(μ-OEt)₂(CO)₉(EPh ₃), 2. These latter clusters are newly synthesized and have been characterized completely, including by single-crystal X-ray crystallographic studies.

Original language	English
Pages (from-to)	753-763
Number of pages	11
Journal	Journal of Cluster Science
Volume	18
Issue number	3
DOIs	https://doi.org/10.1007/s10876-007-0138-5
Publication status	Published - Sept 2007
Externally published	Yes

ASJC Scopus Subject Areas

Biochemistry
General Chemistry
General Materials Science
Condensed Matter Physics

Keywords

Alkoxy
Cluster
EHMO
Osmium
ROP

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10.1007/s10876-007-0138-5

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title = "Reduced overlap population analysis for triosmium clusters",

abstract = "The use of reduced overlap population (ROP) analysis from EHMO calculations as a means to gauge the presence of metal-metal bonds in triosmium clusters is examined. A number of triosmium clusters containing bridging ligands have been used as test cases, including the bis-ethoxy bridged cluster Os 3(μ-OEt)2(CO)10, 1b, and some of its group 15 derivatives Os3(μ-OEt)2(CO)9(EPh 3), 2. These latter clusters are newly synthesized and have been characterized completely, including by single-crystal X-ray crystallographic studies.",

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author = "Morrison, {Elizabeth C.} and Leong, {Weng Kee} and Jialin Tan",

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T1 - Reduced overlap population analysis for triosmium clusters

AU - Morrison, Elizabeth C.

AU - Leong, Weng Kee

AU - Tan, Jialin

PY - 2007/9

Y1 - 2007/9

N2 - The use of reduced overlap population (ROP) analysis from EHMO calculations as a means to gauge the presence of metal-metal bonds in triosmium clusters is examined. A number of triosmium clusters containing bridging ligands have been used as test cases, including the bis-ethoxy bridged cluster Os 3(μ-OEt)2(CO)10, 1b, and some of its group 15 derivatives Os3(μ-OEt)2(CO)9(EPh 3), 2. These latter clusters are newly synthesized and have been characterized completely, including by single-crystal X-ray crystallographic studies.

AB - The use of reduced overlap population (ROP) analysis from EHMO calculations as a means to gauge the presence of metal-metal bonds in triosmium clusters is examined. A number of triosmium clusters containing bridging ligands have been used as test cases, including the bis-ethoxy bridged cluster Os 3(μ-OEt)2(CO)10, 1b, and some of its group 15 derivatives Os3(μ-OEt)2(CO)9(EPh 3), 2. These latter clusters are newly synthesized and have been characterized completely, including by single-crystal X-ray crystallographic studies.

KW - Alkoxy

KW - Cluster

KW - EHMO

KW - Osmium

KW - ROP

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DO - 10.1007/s10876-007-0138-5

M3 - Article

AN - SCOPUS:34548514478

SN - 1040-7278

VL - 18

SP - 753

EP - 763

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 3

ER -

Reduced overlap population analysis for triosmium clusters

Abstract

ASJC Scopus Subject Areas

Keywords

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