Abstract
We demonstrate that polysulfide anions are capable of catalyzing desulfonylation of sulfonamides having a series of aryl and alkyl substituents in the presence of potassium formate under irradiation with visible light. The developed protocol is operationally concise and cost-effective, representing a practical and sustainable synthetic tool for desulfonylation and expanding the chemical space in secondary amine synthesis.
Original language | English |
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Pages (from-to) | 4026-4031 |
Number of pages | 6 |
Journal | Organic Letters |
Volume | 27 |
Issue number | 15 |
DOIs | |
Publication status | Published - Apr 18 2025 |
Externally published | Yes |
ASJC Scopus Subject Areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry