TY - JOUR
T1 - Reversible chain transfer catalyzed polymerization (RTCP) with alcohol catalysts
AU - Goto, Atsushi
AU - Hirai, Norihiro
AU - Wakada, Tsutomu
AU - Nagasawa, Koji
AU - Tsujii, Yoshinobu
AU - Fukuda, Takeshi
PY - 2009/8/13
Y1 - 2009/8/13
N2 - Alcohols (phenols, a vinyl alcohol, and an iodide derivative) worked as efficient catalysts for reversible chain transfer catalyzed polymerization (RTCP). Low-polydispersity (Mw/Mn ∼ 1.2-1.3) polystyrenes and poly(methyl methacrylate)s with predicted molecular weights were obtained with a fairly high conversion. Attractive features of the alcohol catalysts include their high reactivity (a small amount being required), low or no toxicity, and low cost (cheapness).
AB - Alcohols (phenols, a vinyl alcohol, and an iodide derivative) worked as efficient catalysts for reversible chain transfer catalyzed polymerization (RTCP). Low-polydispersity (Mw/Mn ∼ 1.2-1.3) polystyrenes and poly(methyl methacrylate)s with predicted molecular weights were obtained with a fairly high conversion. Attractive features of the alcohol catalysts include their high reactivity (a small amount being required), low or no toxicity, and low cost (cheapness).
UR - http://www.scopus.com/inward/record.url?scp=77649215449&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=77649215449&partnerID=8YFLogxK
U2 - 10.1021/bk-2009-1023.ch011
DO - 10.1021/bk-2009-1023.ch011
M3 - Article
AN - SCOPUS:77649215449
SN - 0097-6156
VL - 1023
SP - 159
EP - 168
JO - ACS Symposium Series
JF - ACS Symposium Series
ER -