Revisiting the Chichibabin Reaction: C2 Amination of Pyridines with a NaH−Iodide Composite

Jia Hao Pang; Atsushi Kaga; Sven Roediger; Min Htoo Lin; Shunsuke Chiba

doi:10.1002/ajoc.201900094

Revisiting the Chichibabin Reaction: C2 Amination of Pyridines with a NaH−Iodide Composite

Jia Hao Pang, Atsushi Kaga, Sven Roediger, Min Htoo Lin, Shunsuke Chiba^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

A NaH-iodide composite was found capable of mediating the Chichibabin amination under mild reaction conditions, allowing efficient access to a range of 2-aminopyridines and their derivatives.

Original language	English
Pages (from-to)	1058-1060
Number of pages	3
Journal	Asian Journal of Organic Chemistry
Volume	8
Issue number	7
DOIs	https://doi.org/10.1002/ajoc.201900094
Publication status	Published - Jul 2019
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

ASJC Scopus Subject Areas

Organic Chemistry

Keywords

Chichibabin amination
C−H activation
hydrides
lithium iodide
pyridines

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10.1002/ajoc.201900094

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title = "Revisiting the Chichibabin Reaction: C2 Amination of Pyridines with a NaH−Iodide Composite",

abstract = "A NaH-iodide composite was found capable of mediating the Chichibabin amination under mild reaction conditions, allowing efficient access to a range of 2-aminopyridines and their derivatives.",

keywords = "Chichibabin amination, C−H activation, hydrides, lithium iodide, pyridines",

author = "Pang, \{Jia Hao\} and Atsushi Kaga and Sven Roediger and Lin, \{Min Htoo\} and Shunsuke Chiba",

note = "Publisher Copyright: {\textcopyright} 2019 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2019",

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T2 - C2 Amination of Pyridines with a NaH−Iodide Composite

AU - Pang, Jia Hao

AU - Kaga, Atsushi

AU - Roediger, Sven

AU - Lin, Min Htoo

AU - Chiba, Shunsuke

PY - 2019/7

Y1 - 2019/7

N2 - A NaH-iodide composite was found capable of mediating the Chichibabin amination under mild reaction conditions, allowing efficient access to a range of 2-aminopyridines and their derivatives.

AB - A NaH-iodide composite was found capable of mediating the Chichibabin amination under mild reaction conditions, allowing efficient access to a range of 2-aminopyridines and their derivatives.

KW - Chichibabin amination

KW - C−H activation

KW - hydrides

KW - lithium iodide

KW - pyridines

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Revisiting the Chichibabin Reaction: C2 Amination of Pyridines with a NaH−Iodide Composite

Abstract

Bibliographical note

ASJC Scopus Subject Areas

Keywords

Access to Document

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