Rhodium(iii)-catalyzed C-H allylation of electron-deficient alkenes with allyl acetates

Chao Feng; Daming Feng; Teck Peng Loh

doi:10.1039/c4cc07597h

Rhodium(iii)-catalyzed C-H allylation of electron-deficient alkenes with allyl acetates

Chao Feng, Daming Feng, Teck Peng Loh^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

80 Citations (Scopus)

Abstract

Rhodium-catalyzed C-H allylation of acrylamides with allyl acetates is reported. The use of weakly coordinating directing group resulted in high reaction efficiency, broad functionality tolerance and excellent γ-selectivity, which opens a new synthetic pathway for the access of 1,4-diene skeletons.

Original language	English
Pages (from-to)	342-345
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	2
DOIs	https://doi.org/10.1039/c4cc07597h
Publication status	Published - Jan 7 2015
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2015 The Royal Society of Chemistry.

ASJC Scopus Subject Areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "Rhodium-catalyzed C-H allylation of acrylamides with allyl acetates is reported. The use of weakly coordinating directing group resulted in high reaction efficiency, broad functionality tolerance and excellent γ-selectivity, which opens a new synthetic pathway for the access of 1,4-diene skeletons.",

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AB - Rhodium-catalyzed C-H allylation of acrylamides with allyl acetates is reported. The use of weakly coordinating directing group resulted in high reaction efficiency, broad functionality tolerance and excellent γ-selectivity, which opens a new synthetic pathway for the access of 1,4-diene skeletons.

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Rhodium(iii)-catalyzed C-H allylation of electron-deficient alkenes with allyl acetates

Abstract

Bibliographical note

ASJC Scopus Subject Areas

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