Rhodium(III)-catalyzed hydroamination of aromatic terminal alkynes with anilines

Elumalai Kumaran; Weng Kee Leong

doi:10.1021/om201134j

Rhodium(III)-catalyzed hydroamination of aromatic terminal alkynes with anilines

Elumalai Kumaran, Weng Kee Leong^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

The dinuclear Rh(III) species [Cp*RhCl ₂] ₂ catalyzes the hydroamination reaction between an aromatic terminal alkyne (ArCCH) and an aniline (Ar′NH ₂), in the presence of a salt additive, to afford the ketimine Ar′N=C(Me)(Ar). A reaction pathway has been proposed on the basis of experimental and computational studies.

Original language	English
Pages (from-to)	1068-1072
Number of pages	5
Journal	Organometallics
Volume	31
Issue number	3
DOIs	https://doi.org/10.1021/om201134j
Publication status	Published - Feb 13 2012
Externally published	Yes

ASJC Scopus Subject Areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Rhodium(III)-catalyzed hydroamination of aromatic terminal alkynes with anilines",

abstract = "The dinuclear Rh(III) species [Cp*RhCl 2] 2 catalyzes the hydroamination reaction between an aromatic terminal alkyne (ArCCH) and an aniline (Ar′NH 2), in the presence of a salt additive, to afford the ketimine Ar′N=C(Me)(Ar). A reaction pathway has been proposed on the basis of experimental and computational studies.",

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AU - Leong, Weng Kee

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N2 - The dinuclear Rh(III) species [Cp*RhCl 2] 2 catalyzes the hydroamination reaction between an aromatic terminal alkyne (ArCCH) and an aniline (Ar′NH 2), in the presence of a salt additive, to afford the ketimine Ar′N=C(Me)(Ar). A reaction pathway has been proposed on the basis of experimental and computational studies.

AB - The dinuclear Rh(III) species [Cp*RhCl 2] 2 catalyzes the hydroamination reaction between an aromatic terminal alkyne (ArCCH) and an aniline (Ar′NH 2), in the presence of a salt additive, to afford the ketimine Ar′N=C(Me)(Ar). A reaction pathway has been proposed on the basis of experimental and computational studies.

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Rhodium(III)-catalyzed hydroamination of aromatic terminal alkynes with anilines

Abstract

ASJC Scopus Subject Areas

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