Rhodium(iii)-catalyzed olefinic C–H alkynylation of enamides at room temperature

Chao Feng; Daming Feng; Teck Peng Loh

doi:10.1039/c4cc04072d

Rhodium(iii)-catalyzed olefinic C–H alkynylation of enamides at room temperature

Chao Feng, Daming Feng, Teck Peng Loh^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

129 Citations (Scopus)

Abstract

Rh(iii)-catalyzed C–H olefinic alkynylation of enamides for the stereospecific construction of synthetically useful Z -type enynamides is reported. This protocol displays good functionality tolerance and operational simplicity thus providing an alternative synthetic opportunity for the ease of access to specific 1,3-enyne derivatives.

Original language	English
Pages (from-to)	9865-9868
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	69
DOIs	https://doi.org/10.1039/c4cc04072d
Publication status	Published - Jul 31 2014
Externally published	Yes

ASJC Scopus Subject Areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c4cc04072d

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abstract = "Rh(iii)-catalyzed C–H olefinic alkynylation of enamides for the stereospecific construction of synthetically useful Z -type enynamides is reported. This protocol displays good functionality tolerance and operational simplicity thus providing an alternative synthetic opportunity for the ease of access to specific 1,3-enyne derivatives.",

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AU - Loh, Teck Peng

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N2 - Rh(iii)-catalyzed C–H olefinic alkynylation of enamides for the stereospecific construction of synthetically useful Z -type enynamides is reported. This protocol displays good functionality tolerance and operational simplicity thus providing an alternative synthetic opportunity for the ease of access to specific 1,3-enyne derivatives.

AB - Rh(iii)-catalyzed C–H olefinic alkynylation of enamides for the stereospecific construction of synthetically useful Z -type enynamides is reported. This protocol displays good functionality tolerance and operational simplicity thus providing an alternative synthetic opportunity for the ease of access to specific 1,3-enyne derivatives.

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Rhodium(iii)-catalyzed olefinic C–H alkynylation of enamides at room temperature

Abstract

ASJC Scopus Subject Areas

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