RhIII-Catalyzed Hydroarylation of Internal Alkynes through C−H Bond Activation

Cheng Qiang Wang; Chao Feng; Teck Peng Loh

doi:10.1002/ajoc.201600144

Rh^III-Catalyzed Hydroarylation of Internal Alkynes through C−H Bond Activation

Cheng Qiang Wang, Chao Feng^*, Teck Peng Loh

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Rh^III-catalyzed hydroarylation of internal alkynes through C−H bond activation is described herein by using N,N-dimethylaminocarbonyl as a directing group without the need of an external oxidant. This protocol exhibits exceptional functionality compatibility owing to its extremely mild reaction conditions, which provides a facile and highly efficient synthetic method for olefin moiety introduction.

Original language	English
Pages (from-to)	1002-1007
Number of pages	6
Journal	Asian Journal of Organic Chemistry
Volume	5
Issue number	8
DOIs	https://doi.org/10.1002/ajoc.201600144
Publication status	Published - Aug 1 2016
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

ASJC Scopus Subject Areas

Organic Chemistry

Keywords

alkynes
cross-coupling
C−H activation
hydroarylation
rhodium

Access to Document

10.1002/ajoc.201600144

Cite this

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