Ring Expansion, Photoisomerization, and Retrocyclization of 1,4,2-Diazaboroles

Bochao Su; Yongxin Li; Rakesh Ganguly; Rei Kinjo

doi:10.1002/anie.201708720

Ring Expansion, Photoisomerization, and Retrocyclization of 1,4,2-Diazaboroles

Bochao Su, Yongxin Li, Rakesh Ganguly, Rei Kinjo^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Diverse skeletal transformations of 1,4,2-diazaboroles through ring expansion, photoisomerization, and retrocyclization led to the isolation of various B,N-dihydroindole (compounds 3 and 6), 1,3-azaborolidin-2-imine (compound 7), and 1,4,2-diazaborol-3-imine derivatives (compound 11).

Original language	English
Pages (from-to)	14572-14576
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	56
Issue number	46
DOIs	https://doi.org/10.1002/anie.201708720
Publication status	Published - Nov 13 2017
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

ASJC Scopus Subject Areas

Catalysis
General Chemistry

Keywords

B,N heterocycles
diazaboroles
photoisomerization
retrocyclization
ring expansion

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10.1002/anie.201708720

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abstract = "Diverse skeletal transformations of 1,4,2-diazaboroles through ring expansion, photoisomerization, and retrocyclization led to the isolation of various B,N-dihydroindole (compounds 3 and 6), 1,3-azaborolidin-2-imine (compound 7), and 1,4,2-diazaborol-3-imine derivatives (compound 11).",

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AU - Su, Bochao

AU - Li, Yongxin

AU - Ganguly, Rakesh

AU - Kinjo, Rei

PY - 2017/11/13

Y1 - 2017/11/13

N2 - Diverse skeletal transformations of 1,4,2-diazaboroles through ring expansion, photoisomerization, and retrocyclization led to the isolation of various B,N-dihydroindole (compounds 3 and 6), 1,3-azaborolidin-2-imine (compound 7), and 1,4,2-diazaborol-3-imine derivatives (compound 11).

AB - Diverse skeletal transformations of 1,4,2-diazaboroles through ring expansion, photoisomerization, and retrocyclization led to the isolation of various B,N-dihydroindole (compounds 3 and 6), 1,3-azaborolidin-2-imine (compound 7), and 1,4,2-diazaborol-3-imine derivatives (compound 11).

KW - B,N heterocycles

KW - diazaboroles

KW - photoisomerization

KW - retrocyclization

KW - ring expansion

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JO - Angewandte Chemie - International Edition

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Ring Expansion, Photoisomerization, and Retrocyclization of 1,4,2-Diazaboroles

Abstract

Bibliographical note

ASJC Scopus Subject Areas

Keywords

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